MALDI and TOF-SIMS study of the initiating species in the anionic ring opening polymerization of hexamethylcyclotrisiloxane (D3)

Adam M. Hawkridge; Joseph A. Gardella

MALDI and TOF-SIMS study of the initiating species in the anionic ring opening polymerization of hexamethylcyclotrisiloxane (D₃)

Adam M. Hawkridge
, Joseph A. Gardella

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Conference article › peer-review

Abstract

Matrix-assisted laser desorption/ionization and time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to investigate the effects of initial sec-butyllithium concentrations on the relative amounts of siloxanolate initiating species. The results have shown MALDI to be a more reproducible method for determining relative intensities than TOF-SIMS.

Original language	English
Pages (from-to)	635-636
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	41
Issue number	1
State	Published - Mar 2000
Event	The San Francisco Meeting - San Francisco, CA, USA Duration: Mar 26 2000 → Mar 31 2000

Cite this

@article{907ea1c4483b47c98d3ef1cb7b57f6cc,

title = "MALDI and TOF-SIMS study of the initiating species in the anionic ring opening polymerization of hexamethylcyclotrisiloxane (D3)",

abstract = "Matrix-assisted laser desorption/ionization and time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to investigate the effects of initial sec-butyllithium concentrations on the relative amounts of siloxanolate initiating species. The results have shown MALDI to be a more reproducible method for determining relative intensities than TOF-SIMS.",

author = "Hawkridge, \{Adam M.\} and Gardella, \{Joseph A.\}",

year = "2000",

month = mar,

language = "English",

volume = "41",

pages = "635--636",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "1",

note = "The San Francisco Meeting ; Conference date: 26-03-2000 Through 31-03-2000",

}

TY - JOUR

T1 - MALDI and TOF-SIMS study of the initiating species in the anionic ring opening polymerization of hexamethylcyclotrisiloxane (D3)

AU - Hawkridge, Adam M.

AU - Gardella, Joseph A.

PY - 2000/3

Y1 - 2000/3

N2 - Matrix-assisted laser desorption/ionization and time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to investigate the effects of initial sec-butyllithium concentrations on the relative amounts of siloxanolate initiating species. The results have shown MALDI to be a more reproducible method for determining relative intensities than TOF-SIMS.

AB - Matrix-assisted laser desorption/ionization and time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to investigate the effects of initial sec-butyllithium concentrations on the relative amounts of siloxanolate initiating species. The results have shown MALDI to be a more reproducible method for determining relative intensities than TOF-SIMS.

UR - https://www.scopus.com/pages/publications/0033750880

M3 - Conference article

AN - SCOPUS:0033750880

SN - 0032-3934

VL - 41

SP - 635

EP - 636

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 1

T2 - The San Francisco Meeting

Y2 - 26 March 2000 through 31 March 2000

ER -

MALDI and TOF-SIMS study of the initiating species in the anionic ring opening polymerization of hexamethylcyclotrisiloxane (D₃)

Abstract

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