Macrocyclic n-heterocyclic carbenes: Synthesis and catalytic applications

Anibal R. Davalos; Eric Sylvester; Steven T. Diver

doi:10.1021/acs.organomet.9b00152

Macrocyclic n-heterocyclic carbenes: Synthesis and catalytic applications

Anibal R. Davalos
, Eric Sylvester
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A synthesis of two macrocyclic N-heterocyclic carbenes (NHCs) is reported. An advanced intermediate could be differentiated to access either imidazolium or dihydroimidazolium salts. Deprotonation gave a nucleophilic carbene that promoted the intramolecular Michael-Stetter reaction.

Original language	English
Pages (from-to)	2338-2346
Number of pages	9
Journal	Organometallics
Volume	38
Issue number	11
DOIs	https://doi.org/10.1021/acs.organomet.9b00152
State	Published - Jun 10 2019

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title = "Macrocyclic n-heterocyclic carbenes: Synthesis and catalytic applications",

abstract = "A synthesis of two macrocyclic N-heterocyclic carbenes (NHCs) is reported. An advanced intermediate could be differentiated to access either imidazolium or dihydroimidazolium salts. Deprotonation gave a nucleophilic carbene that promoted the intramolecular Michael-Stetter reaction.",

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doi = "10.1021/acs.organomet.9b00152",

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T2 - Synthesis and catalytic applications

AU - Davalos, Anibal R.

AU - Sylvester, Eric

AU - Diver, Steven T.

PY - 2019/6/10

Y1 - 2019/6/10

N2 - A synthesis of two macrocyclic N-heterocyclic carbenes (NHCs) is reported. An advanced intermediate could be differentiated to access either imidazolium or dihydroimidazolium salts. Deprotonation gave a nucleophilic carbene that promoted the intramolecular Michael-Stetter reaction.

AB - A synthesis of two macrocyclic N-heterocyclic carbenes (NHCs) is reported. An advanced intermediate could be differentiated to access either imidazolium or dihydroimidazolium salts. Deprotonation gave a nucleophilic carbene that promoted the intramolecular Michael-Stetter reaction.

UR - https://www.scopus.com/pages/publications/85066976456

U2 - 10.1021/acs.organomet.9b00152

DO - 10.1021/acs.organomet.9b00152

M3 - Article

AN - SCOPUS:85066976456

SN - 0276-7333

VL - 38

SP - 2338

EP - 2346

JO - Organometallics

JF - Organometallics

IS - 11

ER -

Macrocyclic n-heterocyclic carbenes: Synthesis and catalytic applications

Abstract

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