Macrocycles consisting of flexible and rigid segments: Enforced folding and host-guest inclusion exciplex formation

Xiaomei Tang; Li Lin; Futao Liu; Xiangjun Yue; Bing Gong; Minfeng Li; Lan He

doi:10.1016/j.tet.2013.07.020

Macrocycles consisting of flexible and rigid segments: Enforced folding and host-guest inclusion exciplex formation

Xiaomei Tang
, Li Lin
, Futao Liu
, Xiangjun Yue
, Bing Gong
, Minfeng Li
, Lan He

Chemistry

Beijing Normal University
National Institutes for Food and Drug Control

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Macrocycles consisting of two tris(phenylene ethynylene) (or tri-PE) units connected via two flexible linkers adopt an 'unfolded' conformation that is converted into a folded conformation upon introducing intramolecular hydrogen bonding interaction. These foldable macrocycles are capable of forming inclusion charge transfer (CT) complex with electron-deficient small aromatics.

Original language	English
Pages (from-to)	8487-8493
Number of pages	7
Journal	Tetrahedron
Volume	69
Issue number	39
DOIs	https://doi.org/10.1016/j.tet.2013.07.020
State	Published - Sep 30 2013

Keywords

Charge transfer complex
Folding
Hydrogen binding
Inclusion complex
Macrocycles

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10.1016/j.tet.2013.07.020

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abstract = "Macrocycles consisting of two tris(phenylene ethynylene) (or tri-PE) units connected via two flexible linkers adopt an 'unfolded' conformation that is converted into a folded conformation upon introducing intramolecular hydrogen bonding interaction. These foldable macrocycles are capable of forming inclusion charge transfer (CT) complex with electron-deficient small aromatics.",

keywords = "Charge transfer complex, Folding, Hydrogen binding, Inclusion complex, Macrocycles",

author = "Xiaomei Tang and Li Lin and Futao Liu and Xiangjun Yue and Bing Gong and Minfeng Li and Lan He",

year = "2013",

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T1 - Macrocycles consisting of flexible and rigid segments

T2 - Enforced folding and host-guest inclusion exciplex formation

AU - Tang, Xiaomei

AU - Lin, Li

AU - Liu, Futao

AU - Yue, Xiangjun

AU - Gong, Bing

AU - Li, Minfeng

AU - He, Lan

PY - 2013/9/30

Y1 - 2013/9/30

N2 - Macrocycles consisting of two tris(phenylene ethynylene) (or tri-PE) units connected via two flexible linkers adopt an 'unfolded' conformation that is converted into a folded conformation upon introducing intramolecular hydrogen bonding interaction. These foldable macrocycles are capable of forming inclusion charge transfer (CT) complex with electron-deficient small aromatics.

AB - Macrocycles consisting of two tris(phenylene ethynylene) (or tri-PE) units connected via two flexible linkers adopt an 'unfolded' conformation that is converted into a folded conformation upon introducing intramolecular hydrogen bonding interaction. These foldable macrocycles are capable of forming inclusion charge transfer (CT) complex with electron-deficient small aromatics.

KW - Charge transfer complex

KW - Folding

KW - Hydrogen binding

KW - Inclusion complex

KW - Macrocycles

UR - https://www.scopus.com/pages/publications/84882250649

U2 - 10.1016/j.tet.2013.07.020

DO - 10.1016/j.tet.2013.07.020

M3 - Article

AN - SCOPUS:84882250649

SN - 0040-4020

VL - 69

SP - 8487

EP - 8493

JO - Tetrahedron

JF - Tetrahedron

IS - 39

ER -

Macrocycles consisting of flexible and rigid segments: Enforced folding and host-guest inclusion exciplex formation

Abstract

Keywords

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