Ligand substitution on HRu3(μ-NC5H3CO2Me)(CO) 10 and H2Ru3(μ-NC5H3CO 2Me)2(CO)8. Crystal structures of (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3)

Melvyn Rowen Churchill; Robert Hall; Charles H. Lake; Laurence M. Toomey; Jerome B. Keister

doi:10.1080/00958979908023055

Ligand substitution on HRu₃(μ-NC₅H₃CO₂Me)(CO) ₁₀ and H₂Ru₃(μ-NC₅H₃CO ₂Me)₂(CO)₈. Crystal structures of (μ-H)Ru₃(μ-η²-NC₅H₃CO ₂Me)(CO)₉(PPh₃)

Melvyn Rowen Churchill
, Robert Hall
, Charles H. Lake
, Laurence M. Toomey
, Jerome B. Keister

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

Abstract

Clusters of the series HRu₂(μ-NC₅H₃CO₂Me)(CO) _10-n(PPh₃)_n (n = 0,1) and H₂Ru₃(μ-NC₅H₃CO ₂Me)₂(CO)_8-n(PPh₃)_n (n = 0,1) have been prepared. X-ray crystallographic studies of HRu₃(μ-NC₅H₃-5-CO₂Me)(CO) ₉(PPh₃) and H₂Ru₃(μ-NC₅H₃-5-CO ₂Me)₂(CO)₇(PPh₃) have been performed. The regiochemistry of PPh₃ substitution in both is consistent with greater cis labilization by the N-donor atom compared with the C-donor atom of the nicotinyl ligand. The monohydrido-methyl nicotinate derivative, (μ-H)Ru₃(μ-η²-NC₅H₃CO ₂Me)(CO)₉(PPh₃), crystallizes in the orthorhombic space group Pbca (No. 61) with a = 22.891(3), b= 12.641(1), c = 24.694(3) Å, V=7145.6(14)Å³and Z = 8. The structure was solved and refined to R = 2.60% for 2191 data with |F₀| ≥ 6σ(F₀). The Ru₃ triangle has interatomic distances (in increasing order) of Ru(1)-Ru(3) = 2.854(1), Ru(2)-Ru(3) = 2.861(1) and Ru(1)-Ru(2) = 2.910(1)Å.

Original language	English
Pages (from-to)	211-229
Number of pages	19
Journal	Journal of Coordination Chemistry
Volume	47
Issue number	2
DOIs	https://doi.org/10.1080/00958979908023055
State	Published - 1999

Access to Document

10.1080/00958979908023055

Cite this

@article{6aba83ef5b534c2fb9d151d927d0f048,

title = "Ligand substitution on HRu3(μ-NC5H3CO2Me)(CO) 10 and H2Ru3(μ-NC5H3CO 2Me)2(CO)8. Crystal structures of (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3)",

abstract = "Clusters of the series HRu2(μ-NC5H3CO2Me)(CO) 10-n(PPh3)n (n = 0,1) and H2Ru3(μ-NC5H3CO 2Me)2(CO)8-n(PPh3)n (n = 0,1) have been prepared. X-ray crystallographic studies of HRu3(μ-NC5H3-5-CO2Me)(CO) 9(PPh3) and H2Ru3(μ-NC5H3-5-CO 2Me)2(CO)7(PPh3) have been performed. The regiochemistry of PPh3 substitution in both is consistent with greater cis labilization by the N-donor atom compared with the C-donor atom of the nicotinyl ligand. The monohydrido-methyl nicotinate derivative, (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3), crystallizes in the orthorhombic space group Pbca (No. 61) with a = 22.891(3), b= 12.641(1), c = 24.694(3) {\AA}, V=7145.6(14){\AA}3and Z = 8. The structure was solved and refined to R = 2.60\% for 2191 data with |F0| ≥ 6σ(F0). The Ru3 triangle has interatomic distances (in increasing order) of Ru(1)-Ru(3) = 2.854(1), Ru(2)-Ru(3) = 2.861(1) and Ru(1)-Ru(2) = 2.910(1){\AA}.",

author = "Churchill, \{Melvyn Rowen\} and Robert Hall and Lake, \{Charles H.\} and Toomey, \{Laurence M.\} and Keister, \{Jerome B.\}",

year = "1999",

doi = "10.1080/00958979908023055",

language = "English",

volume = "47",

pages = "211--229",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "2",

}

TY - JOUR

T1 - Ligand substitution on HRu3(μ-NC5H3CO2Me)(CO) 10 and H2Ru3(μ-NC5H3CO 2Me)2(CO)8. Crystal structures of (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3)

AU - Churchill, Melvyn Rowen

AU - Hall, Robert

AU - Lake, Charles H.

AU - Toomey, Laurence M.

AU - Keister, Jerome B.

PY - 1999

Y1 - 1999

N2 - Clusters of the series HRu2(μ-NC5H3CO2Me)(CO) 10-n(PPh3)n (n = 0,1) and H2Ru3(μ-NC5H3CO 2Me)2(CO)8-n(PPh3)n (n = 0,1) have been prepared. X-ray crystallographic studies of HRu3(μ-NC5H3-5-CO2Me)(CO) 9(PPh3) and H2Ru3(μ-NC5H3-5-CO 2Me)2(CO)7(PPh3) have been performed. The regiochemistry of PPh3 substitution in both is consistent with greater cis labilization by the N-donor atom compared with the C-donor atom of the nicotinyl ligand. The monohydrido-methyl nicotinate derivative, (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3), crystallizes in the orthorhombic space group Pbca (No. 61) with a = 22.891(3), b= 12.641(1), c = 24.694(3) Å, V=7145.6(14)Å3and Z = 8. The structure was solved and refined to R = 2.60% for 2191 data with |F0| ≥ 6σ(F0). The Ru3 triangle has interatomic distances (in increasing order) of Ru(1)-Ru(3) = 2.854(1), Ru(2)-Ru(3) = 2.861(1) and Ru(1)-Ru(2) = 2.910(1)Å.

AB - Clusters of the series HRu2(μ-NC5H3CO2Me)(CO) 10-n(PPh3)n (n = 0,1) and H2Ru3(μ-NC5H3CO 2Me)2(CO)8-n(PPh3)n (n = 0,1) have been prepared. X-ray crystallographic studies of HRu3(μ-NC5H3-5-CO2Me)(CO) 9(PPh3) and H2Ru3(μ-NC5H3-5-CO 2Me)2(CO)7(PPh3) have been performed. The regiochemistry of PPh3 substitution in both is consistent with greater cis labilization by the N-donor atom compared with the C-donor atom of the nicotinyl ligand. The monohydrido-methyl nicotinate derivative, (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3), crystallizes in the orthorhombic space group Pbca (No. 61) with a = 22.891(3), b= 12.641(1), c = 24.694(3) Å, V=7145.6(14)Å3and Z = 8. The structure was solved and refined to R = 2.60% for 2191 data with |F0| ≥ 6σ(F0). The Ru3 triangle has interatomic distances (in increasing order) of Ru(1)-Ru(3) = 2.854(1), Ru(2)-Ru(3) = 2.861(1) and Ru(1)-Ru(2) = 2.910(1)Å.

UR - https://www.scopus.com/pages/publications/8744316160

U2 - 10.1080/00958979908023055

DO - 10.1080/00958979908023055

M3 - Article

AN - SCOPUS:8744316160

SN - 0095-8972

VL - 47

SP - 211

EP - 229

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 2

ER -

Ligand substitution on HRu₃(μ-NC₅H₃CO₂Me)(CO) ₁₀ and H₂Ru₃(μ-NC₅H₃CO ₂Me)₂(CO)₈. Crystal structures of (μ-H)Ru₃(μ-η²-NC₅H₃CO ₂Me)(CO)₉(PPh₃)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this