Ligand and metal effects on the reactivity of metal carbonyls

Jim D. Atwood

doi:10.1016/0022-328X(90)85122-F

Ligand and metal effects on the reactivity of metal carbonyls

Jim D. Atwood

Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reactivity of metal carbonyl complexes is surveyed. The effect of charge, electron count, row and electronic configuration of the metal are examined for mononuclear carbonyls and more limited information is examined for metal clusters. Ligand effects are also examined for the metal carbonyls. The reactivity of metal carbonyl complexes changes by at least 15 orders of magnitude. This paper provides a framework for understanding such a range of reactivity.

Original language	English
Pages (from-to)	59-69
Number of pages	11
Journal	Journal of Organometallic Chemistry
Volume	383
Issue number	1-3
DOIs	https://doi.org/10.1016/0022-328X(90)85122-F
State	Published - Feb 20 1990

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10.1016/0022-328X(90)85122-F

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title = "Ligand and metal effects on the reactivity of metal carbonyls",

abstract = "The reactivity of metal carbonyl complexes is surveyed. The effect of charge, electron count, row and electronic configuration of the metal are examined for mononuclear carbonyls and more limited information is examined for metal clusters. Ligand effects are also examined for the metal carbonyls. The reactivity of metal carbonyl complexes changes by at least 15 orders of magnitude. This paper provides a framework for understanding such a range of reactivity.",

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T1 - Ligand and metal effects on the reactivity of metal carbonyls

AU - Atwood, Jim D.

PY - 1990/2/20

Y1 - 1990/2/20

N2 - The reactivity of metal carbonyl complexes is surveyed. The effect of charge, electron count, row and electronic configuration of the metal are examined for mononuclear carbonyls and more limited information is examined for metal clusters. Ligand effects are also examined for the metal carbonyls. The reactivity of metal carbonyl complexes changes by at least 15 orders of magnitude. This paper provides a framework for understanding such a range of reactivity.

AB - The reactivity of metal carbonyl complexes is surveyed. The effect of charge, electron count, row and electronic configuration of the metal are examined for mononuclear carbonyls and more limited information is examined for metal clusters. Ligand effects are also examined for the metal carbonyls. The reactivity of metal carbonyl complexes changes by at least 15 orders of magnitude. This paper provides a framework for understanding such a range of reactivity.

UR - https://www.scopus.com/pages/publications/0011601397

U2 - 10.1016/0022-328X(90)85122-F

DO - 10.1016/0022-328X(90)85122-F

M3 - Article

AN - SCOPUS:0011601397

SN - 0022-328X

VL - 383

SP - 59

EP - 69

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-3

ER -

Ligand and metal effects on the reactivity of metal carbonyls

Abstract

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