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Kinetics of intercalation and desorption in graphite

  • K. K. Bardhan
  • , J. C. Wu
  • , J. S. Culik
  • , S. H. Anderson
  • , D. D.L. Chung
  • Department of Physics
  • Department of Electrical Engineering
  • Carnegie Mellon University

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

The kinetics of intercalation was studied by measuring the surface profile on the cface and the expansion at the edge during intercalation. A phenomenological model of interface-controlled intercalation is presented and agreement between the model and various experimental results is shown. The kinetics of desorption was studied by using surface profilometry, gas detection and thermogravimetry. These experimental results suggests a phenomenological model of desorption, which considers the out-diffusion of the intercalate.

Original languageEnglish
Pages (from-to)57-84
Number of pages28
JournalSynthetic Metals
Volume2
Issue number1-2
DOIs
StatePublished - 1980

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