Isocyanide-promoted ylidene transfer to phosphorus: Rearrangement in the first-generation grubbs complex

Brandon R. Galan; Mateusz Pitak; Jerome B. Keister; Steven T. Diver

doi:10.1021/om8003652

Isocyanide-promoted ylidene transfer to phosphorus: Rearrangement in the first-generation grubbs complex

Brandon R. Galan
, Mateusz Pitak
, Jerome B. Keister
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.

Original language	English
Pages (from-to)	3630-3632
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	15
DOIs	https://doi.org/10.1021/om8003652
State	Published - Aug 11 2008

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10.1021/om8003652

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title = "Isocyanide-promoted ylidene transfer to phosphorus: Rearrangement in the first-generation grubbs complex",

abstract = "Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.",

author = "Galan, \{Brandon R.\} and Mateusz Pitak and Keister, \{Jerome B.\} and Diver, \{Steven T.\}",

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journal = "Organometallics",

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T1 - Isocyanide-promoted ylidene transfer to phosphorus

T2 - Rearrangement in the first-generation grubbs complex

AU - Galan, Brandon R.

AU - Pitak, Mateusz

AU - Keister, Jerome B.

AU - Diver, Steven T.

PY - 2008/8/11

Y1 - 2008/8/11

N2 - Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.

AB - Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.

UR - https://www.scopus.com/pages/publications/50549094536

U2 - 10.1021/om8003652

DO - 10.1021/om8003652

M3 - Article

AN - SCOPUS:50549094536

SN - 0276-7333

VL - 27

SP - 3630

EP - 3632

JO - Organometallics

JF - Organometallics

IS - 15

ER -

Isocyanide-promoted ylidene transfer to phosphorus: Rearrangement in the first-generation grubbs complex

Abstract

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