Intermolecular enol ether-alkyne metathesis

Anthony J. Giessert; Lee Snyder; Jordan Markham; Steven T. Diver

doi:10.1021/ol034459k

Intermolecular enol ether-alkyne metathesis

Anthony J. Giessert
, Lee Snyder
, Jordan Markham
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

(Matrix presented) A new intermolecular metathesis between a variety of alkynes and alkyl enol ethers is described. The best results were obtained with the second generation Grubbs' precatalysts. The reaction occurred with a high degree of regioselectivity and provided electron-rich dienes, which underwent a variety of [4 + 2] cycloadditions.

Original language	English
Pages (from-to)	1793-1796
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	10
DOIs	https://doi.org/10.1021/ol034459k
State	Published - May 15 2003

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10.1021/ol034459k

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title = "Intermolecular enol ether-alkyne metathesis",

abstract = "(Matrix presented) A new intermolecular metathesis between a variety of alkynes and alkyl enol ethers is described. The best results were obtained with the second generation Grubbs' precatalysts. The reaction occurred with a high degree of regioselectivity and provided electron-rich dienes, which underwent a variety of [4 + 2] cycloadditions.",

author = "Giessert, \{Anthony J.\} and Lee Snyder and Jordan Markham and Diver, \{Steven T.\}",

year = "2003",

month = may,

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doi = "10.1021/ol034459k",

language = "English",

volume = "5",

pages = "1793--1796",

journal = "Organic Letters",

issn = "1523-7060",

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T1 - Intermolecular enol ether-alkyne metathesis

AU - Giessert, Anthony J.

AU - Snyder, Lee

AU - Markham, Jordan

AU - Diver, Steven T.

PY - 2003/5/15

Y1 - 2003/5/15

N2 - (Matrix presented) A new intermolecular metathesis between a variety of alkynes and alkyl enol ethers is described. The best results were obtained with the second generation Grubbs' precatalysts. The reaction occurred with a high degree of regioselectivity and provided electron-rich dienes, which underwent a variety of [4 + 2] cycloadditions.

AB - (Matrix presented) A new intermolecular metathesis between a variety of alkynes and alkyl enol ethers is described. The best results were obtained with the second generation Grubbs' precatalysts. The reaction occurred with a high degree of regioselectivity and provided electron-rich dienes, which underwent a variety of [4 + 2] cycloadditions.

UR - https://www.scopus.com/pages/publications/0042229213

U2 - 10.1021/ol034459k

DO - 10.1021/ol034459k

M3 - Article

C2 - 12735779

AN - SCOPUS:0042229213

SN - 1523-7060

VL - 5

SP - 1793

EP - 1796

JO - Organic Letters

JF - Organic Letters

IS - 10

ER -

Intermolecular enol ether-alkyne metathesis

Abstract

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