Interconversion between platinum (II) and platinum (0) with change of pH: Aqueous reactions of Pt(H)(TPPTS)3+ (TPPTS = P(m-C6H4SO3Na)3)

Derrik S. Helfer; Jim D. Atwood

doi:10.1021/om010896w

Interconversion between platinum (II) and platinum (0) with change of pH: Aqueous reactions of Pt(H)(TPPTS)₃⁺ (TPPTS = P(m-C₆H₄SO₃Na)₃)

Derrik S. Helfer
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The interconversion between platinum(II) and platinum(0) with change of pH was investigated. It was shown that the oxidation state for platinum complexes can be controlled through variation of the pH of an aqueous solution. As the pH was decreased in water, the color changed from light yellow to orange.

Original language	English
Pages (from-to)	250-252
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	2
DOIs	https://doi.org/10.1021/om010896w
State	Published - Feb 4 2002

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title = "Interconversion between platinum (II) and platinum (0) with change of pH: Aqueous reactions of Pt(H)(TPPTS)3+ (TPPTS = P(m-C6H4SO3Na)3)",

abstract = "The interconversion between platinum(II) and platinum(0) with change of pH was investigated. It was shown that the oxidation state for platinum complexes can be controlled through variation of the pH of an aqueous solution. As the pH was decreased in water, the color changed from light yellow to orange.",

author = "Helfer, \{Derrik S.\} and Atwood, \{Jim D.\}",

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T2 - Aqueous reactions of Pt(H)(TPPTS)3+ (TPPTS = P(m-C6H4SO3Na)3)

AU - Helfer, Derrik S.

AU - Atwood, Jim D.

PY - 2002/2/4

Y1 - 2002/2/4

N2 - The interconversion between platinum(II) and platinum(0) with change of pH was investigated. It was shown that the oxidation state for platinum complexes can be controlled through variation of the pH of an aqueous solution. As the pH was decreased in water, the color changed from light yellow to orange.

AB - The interconversion between platinum(II) and platinum(0) with change of pH was investigated. It was shown that the oxidation state for platinum complexes can be controlled through variation of the pH of an aqueous solution. As the pH was decreased in water, the color changed from light yellow to orange.

UR - https://www.scopus.com/pages/publications/0001305354

U2 - 10.1021/om010896w

DO - 10.1021/om010896w

M3 - Article

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JO - Organometallics

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Interconversion between platinum (II) and platinum (0) with change of pH: Aqueous reactions of Pt(H)(TPPTS)₃⁺ (TPPTS = P(m-C₆H₄SO₃Na)₃)

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