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Hyperbranched polysiloxysilane nanoparticles for nonviral gene delivery vectors and nanoprobes

  • Won Jin Kim
  • , Adela C. Bonoiu
  • , Kwang Sup Lee
  • , Teruaki Hayakawa
  • , Cheng Xia
  • , Masa Aki Kakimoto
  • , Haridas E. Pudavar
  • , Paras N. Prasad
  • Hannam University
  • SUNY Buffalo
  • Institute of Science Tokyo

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Scopus citations

Abstract

We report an approach to produce predefined surface charge tunable gene delivery vectors using siloxysilsane-based polymer for gene delivery studies. To obtain nonviral vectors, new series of hyperbranched polysiloxysilane (HBPS) were synthesized, and the end groups in polymer structures have modified with hydrophilic molecules; in other words, carboxylic acid and quaternary ammonium groups were employed into terminal structures to give the amphiphilicity. The novelty of these amphiphilic HBPS polymers lies in the fact that nanoparticles with different zeta potential (surface charge density) can be easily tailored and functionalized. These polymeric nanoparticles which containing various chemical groups on the surface indicated altered surface charge distributions (from -40 to +64mV). Finally, the use of these nanoparticles as efficient gene delivery vectors was demonstrated by means of in vitro transfection study using β- galactosidase plasmid and pEGFP-N1 plasmid, and the most efficient combination was obtained using HBPS-CN30:70.

Original languageEnglish
Title of host publicationNanobiosystems
Subtitle of host publicationProcessing, Characterization, and Applications II
DOIs
StatePublished - 2009
EventNanobiosystems: Processing, Characterization, and Applications II - San Diego, CA, United States
Duration: Aug 5 2009Aug 6 2009

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume7403
ISSN (Print)0277-786X

Conference

ConferenceNanobiosystems: Processing, Characterization, and Applications II
Country/TerritoryUnited States
CitySan Diego, CA
Period08/5/0908/6/09

Keywords

  • Hyperbranched polysiloxysilane
  • Multi-photon cellular imaging.
  • Nanoprobe
  • Nonviral gene delivery vector
  • Polymer nanoparticle
  • Surface charge

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