Hydrolysis of an iridium-methyl bond, formation of trans-[Ir(CO)(OH)L2] from trans-[Ir(CO)MeL2] [L = PPh2(m-C6H4SO3Na), PPh2(m-C6H4SO3K) or P(C6H4SO3Na)3] upon dissolving in water

David P. Paterniti; Jim D. Atwood

doi:10.1039/a702197f

Hydrolysis of an iridium-methyl bond, formation of trans-[Ir(CO)(OH)L₂] from trans-[Ir(CO)MeL₂] [L = PPh₂(m-C₆H₄SO₃Na), PPh₂(m-C₆H₄SO₃K) or P(C₆H₄SO₃Na)₃] upon dissolving in water

David P. Paterniti
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL₂] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L₂] and CH₄ are reported.

Original language	English
Pages (from-to)	1665
Number of pages	1
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/a702197f
State	Published - 1997

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title = "Hydrolysis of an iridium-methyl bond, formation of trans-[Ir(CO)(OH)L2] from trans-[Ir(CO)MeL2] [L = PPh2(m-C6H4SO3Na), PPh2(m-C6H4SO3K) or P(C6H4SO3Na)3] upon dissolving in water",

abstract = "The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL2] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L2] and CH4 are reported.",

author = "Paterniti, \{David P.\} and Atwood, \{Jim D.\}",

year = "1997",

doi = "10.1039/a702197f",

language = "English",

pages = "1665",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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TY - JOUR

T1 - Hydrolysis of an iridium-methyl bond, formation of trans-[Ir(CO)(OH)L2] from trans-[Ir(CO)MeL2] [L = PPh2(m-C6H4SO3Na), PPh2(m-C6H4SO3K) or P(C6H4SO3Na)3] upon dissolving in water

AU - Paterniti, David P.

AU - Atwood, Jim D.

PY - 1997

Y1 - 1997

N2 - The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL2] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L2] and CH4 are reported.

AB - The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL2] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L2] and CH4 are reported.

UR - https://www.scopus.com/pages/publications/0011663097

U2 - 10.1039/a702197f

DO - 10.1039/a702197f

M3 - Article

AN - SCOPUS:0011663097

SN - 1359-7345

SP - 1665

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Hydrolysis of an iridium-methyl bond, formation of trans-[Ir(CO)(OH)L₂] from trans-[Ir(CO)MeL₂] [L = PPh₂(m-C₆H₄SO₃Na), PPh₂(m-C₆H₄SO₃K) or P(C₆H₄SO₃Na)₃] upon dissolving in water

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