Hydrogenation of O-methylated carbon monoxide on clusters of the iron triad

Jerome B. Keister

doi:10.1039/C39790000214

Hydrogenation of O-methylated carbon monoxide on clusters of the iron triad

Jerome B. Keister

Chemistry

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Abstract

The carbyne cluster [HM₃(μ₂-COMe)(CO) ₁₀], M = Fe, Ru, or Os, formed by methylation of the corresponding [HM₃(μ₂-CO)(CO)₁₀] anion, react under mild conditions with hydrogen to give [H₃M₃(μ₃- COMe)(CO)₉]; [H₃Ru₃(μ₃-COMe)(CO) ₉] reacts with CO:H₂ (1:1) under more vigorous conditions to form dimethyl ether and [Ru₃(CO)₁₂].

Original language	English
Pages (from-to)	214-215
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39790000214
State	Published - 1979

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title = "Hydrogenation of O-methylated carbon monoxide on clusters of the iron triad",

abstract = "The carbyne cluster [HM3(μ2-COMe)(CO) 10], M = Fe, Ru, or Os, formed by methylation of the corresponding [HM3(μ2-CO)(CO)10] anion, react under mild conditions with hydrogen to give [H3M3(μ3- COMe)(CO)9]; [H3Ru3(μ3-COMe)(CO) 9] reacts with CO:H2 (1:1) under more vigorous conditions to form dimethyl ether and [Ru3(CO)12].",

author = "Keister, \{Jerome B.\}",

year = "1979",

doi = "10.1039/C39790000214",

language = "English",

pages = "214--215",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "5",

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T1 - Hydrogenation of O-methylated carbon monoxide on clusters of the iron triad

AU - Keister, Jerome B.

PY - 1979

Y1 - 1979

N2 - The carbyne cluster [HM3(μ2-COMe)(CO) 10], M = Fe, Ru, or Os, formed by methylation of the corresponding [HM3(μ2-CO)(CO)10] anion, react under mild conditions with hydrogen to give [H3M3(μ3- COMe)(CO)9]; [H3Ru3(μ3-COMe)(CO) 9] reacts with CO:H2 (1:1) under more vigorous conditions to form dimethyl ether and [Ru3(CO)12].

AB - The carbyne cluster [HM3(μ2-COMe)(CO) 10], M = Fe, Ru, or Os, formed by methylation of the corresponding [HM3(μ2-CO)(CO)10] anion, react under mild conditions with hydrogen to give [H3M3(μ3- COMe)(CO)9]; [H3Ru3(μ3-COMe)(CO) 9] reacts with CO:H2 (1:1) under more vigorous conditions to form dimethyl ether and [Ru3(CO)12].

UR - https://www.scopus.com/pages/publications/37049112599

U2 - 10.1039/C39790000214

DO - 10.1039/C39790000214

M3 - Article

AN - SCOPUS:37049112599

SN - 0022-4936

SP - 214

EP - 215

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 5

ER -

Hydrogenation of O-methylated carbon monoxide on clusters of the iron triad

Abstract

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