High density, vertically-aligned carbon nanotube membranes

A method is presented to prepare high-density, vertically-aligned carbon nanotube (VA-CNT) membranes. The CNT arrays were prepared by chemical vapor deposition (CVD), and the arrays were collapsed into dense membranes by capillary-forces due to solvent evaporation. The average space between the CNTs after shrinkage was ∼ 3 nm, which is comparable to the pore size of the CNTs. Thus, the interstitial pores between CNTs were not sealed, and gas permeated through both CNTs and interstitial pores. Nano-filtration of gold nanoparticles and N2 adsorption indicated the pore diameters were approximately 3 nm. Gas permeances, based on total membrane area, were 1 to 4 orders of magnitude higher than VA-CNT membranes in the literature, and gas permeabilities were 4 to 7 orders of magnitude higher than literature values. Gas permeances were approximately 450 times those predicted for Knudsen diffusion, and ideal selectivities were similar to or higher than Knudsen selectivities. These membranes separated a larger molecule (triisopropyl orthoformate (TIPO)) from a smaller molecule (n-hexane) during pervaporation, possibly due to the preferential adsorption, which indicates separation potential for liquid mixtures.