Helicene-grafted vinyl- and carbene-osmium complexes: An example of acid–base chiroptical switching

Emmanuel Anger; Monika Srebro; Nicolas Vanthuyne; Roussel Roussel; Loïc Toupet; Jochen Autschbach; Régis Réau; Jeanne Crassous

doi:10.1039/c3cc47825d

Helicene-grafted vinyl- and carbene-osmium complexes: An example of acid–base chiroptical switching

Emmanuel Anger
, Monika Srebro
, Nicolas Vanthuyne
, Roussel Roussel
, Loïc Toupet
, Jochen Autschbach
, Régis Réau
, Jeanne Crassous

Chemistry

Institut des Sciences Chimiques de Rennes
Jagiellonian University in Kraków
Aix Marseille University

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The first helicene-based carbene-osmium complex has been prepared from a vinyl-osmium derivative and this system has been shown to behave as a potential acid–base triggered chiroptical switch.

Original language	English
Pages (from-to)	2854-2856
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	22
DOIs	https://doi.org/10.1039/c3cc47825d
State	Published - Feb 18 2014

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title = "Helicene-grafted vinyl- and carbene-osmium complexes: An example of acid–base chiroptical switching",

abstract = "The first helicene-based carbene-osmium complex has been prepared from a vinyl-osmium derivative and this system has been shown to behave as a potential acid–base triggered chiroptical switch.",

author = "Emmanuel Anger and Monika Srebro and Nicolas Vanthuyne and Roussel Roussel and Lo{\"i}c Toupet and Jochen Autschbach and R{\'e}gis R{\'e}au and Jeanne Crassous",

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T2 - An example of acid–base chiroptical switching

AU - Anger, Emmanuel

AU - Srebro, Monika

AU - Vanthuyne, Nicolas

AU - Roussel, Roussel

AU - Toupet, Loïc

AU - Autschbach, Jochen

AU - Réau, Régis

AU - Crassous, Jeanne

PY - 2014/2/18

Y1 - 2014/2/18

N2 - The first helicene-based carbene-osmium complex has been prepared from a vinyl-osmium derivative and this system has been shown to behave as a potential acid–base triggered chiroptical switch.

AB - The first helicene-based carbene-osmium complex has been prepared from a vinyl-osmium derivative and this system has been shown to behave as a potential acid–base triggered chiroptical switch.

UR - https://www.scopus.com/pages/publications/84894414447

U2 - 10.1039/c3cc47825d

DO - 10.1039/c3cc47825d

M3 - Article

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SN - 1359-7345

VL - 50

SP - 2854

EP - 2856

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Helicene-grafted vinyl- and carbene-osmium complexes: An example of acid–base chiroptical switching

Abstract

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