Harnessing thorium(IV) as a catalyst: RNA and phosphate diester cleavage by a thorium(IV) macrocyclic complex

C. Wang; S. Choudhary; C. B. Vink; E. A. Secord; J. R. Morrow

doi:10.1039/b005866l

Harnessing thorium(IV) as a catalyst: RNA and phosphate diester cleavage by a thorium(IV) macrocyclic complex

C. Wang
, S. Choudhary
, C. B. Vink
, E. A. Secord
, J. R. Morrow

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A robust macrocyclic tetraamide complex of Th(IV) binds phosphate diesters and promotes cleavage of RNA and phosphate diesters at 37 °C in the pH range 5.00-7.90.

Original language	English
Pages (from-to)	2509-2510
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b005866l
State	Published - Dec 21 2000

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title = "Harnessing thorium(IV) as a catalyst: RNA and phosphate diester cleavage by a thorium(IV) macrocyclic complex",

abstract = "A robust macrocyclic tetraamide complex of Th(IV) binds phosphate diesters and promotes cleavage of RNA and phosphate diesters at 37 °C in the pH range 5.00-7.90.",

author = "C. Wang and S. Choudhary and Vink, \{C. B.\} and Secord, \{E. A.\} and Morrow, \{J. R.\}",

year = "2000",

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T2 - RNA and phosphate diester cleavage by a thorium(IV) macrocyclic complex

AU - Wang, C.

AU - Choudhary, S.

AU - Vink, C. B.

AU - Secord, E. A.

AU - Morrow, J. R.

PY - 2000/12/21

Y1 - 2000/12/21

N2 - A robust macrocyclic tetraamide complex of Th(IV) binds phosphate diesters and promotes cleavage of RNA and phosphate diesters at 37 °C in the pH range 5.00-7.90.

AB - A robust macrocyclic tetraamide complex of Th(IV) binds phosphate diesters and promotes cleavage of RNA and phosphate diesters at 37 °C in the pH range 5.00-7.90.

UR - https://www.scopus.com/pages/publications/0034700578

U2 - 10.1039/b005866l

DO - 10.1039/b005866l

M3 - Article

AN - SCOPUS:0034700578

SN - 1359-7345

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EP - 2510

JO - Chemical Communications

JF - Chemical Communications

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ER -

Harnessing thorium(IV) as a catalyst: RNA and phosphate diester cleavage by a thorium(IV) macrocyclic complex

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