Halide exchange reactions between CpW(CO)3- and CpMo(CO)3X

William S. Striejewske; Jim D. Atwood

doi:10.1080/00958979608022700

Halide exchange reactions between CpW(CO)₃^- and CpMo(CO)₃X

William S. Striejewske
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Halogen atom transfer from CpMo(CO)₃X (X = Cl, Br and I) to CpW(CO)₃^- forming CpMo(CO)₃^- and CpW(CO)₃X occurs with a first-order dependence on the oxidant and the reductant. The rate constants show a very small dependence on the identity of X, suggesting a mechanism involving nucleophilic attack by CpW(CO)₃^- on a carbonyl of CpMo(CO)₃X.

Original language	English
Pages (from-to)	145-149
Number of pages	5
Journal	Journal of Coordination Chemistry
Volume	38
Issue number	1-2
DOIs	https://doi.org/10.1080/00958979608022700
State	Published - 1996

Keywords

Atom transfer
Electron transfer
Halide exchange
Kinetics
Metal carbonyl anions

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title = "Halide exchange reactions between CpW(CO)3- and CpMo(CO)3X",

abstract = "Halogen atom transfer from CpMo(CO)3X (X = Cl, Br and I) to CpW(CO)3- forming CpMo(CO)3- and CpW(CO)3X occurs with a first-order dependence on the oxidant and the reductant. The rate constants show a very small dependence on the identity of X, suggesting a mechanism involving nucleophilic attack by CpW(CO)3- on a carbonyl of CpMo(CO)3X.",

keywords = "Atom transfer, Electron transfer, Halide exchange, Kinetics, Metal carbonyl anions",

author = "Striejewske, \{William S.\} and Atwood, \{Jim D.\}",

year = "1996",

doi = "10.1080/00958979608022700",

language = "English",

volume = "38",

pages = "145--149",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "1-2",

}

TY - JOUR

T1 - Halide exchange reactions between CpW(CO)3- and CpMo(CO)3X

AU - Striejewske, William S.

AU - Atwood, Jim D.

PY - 1996

Y1 - 1996

N2 - Halogen atom transfer from CpMo(CO)3X (X = Cl, Br and I) to CpW(CO)3- forming CpMo(CO)3- and CpW(CO)3X occurs with a first-order dependence on the oxidant and the reductant. The rate constants show a very small dependence on the identity of X, suggesting a mechanism involving nucleophilic attack by CpW(CO)3- on a carbonyl of CpMo(CO)3X.

AB - Halogen atom transfer from CpMo(CO)3X (X = Cl, Br and I) to CpW(CO)3- forming CpMo(CO)3- and CpW(CO)3X occurs with a first-order dependence on the oxidant and the reductant. The rate constants show a very small dependence on the identity of X, suggesting a mechanism involving nucleophilic attack by CpW(CO)3- on a carbonyl of CpMo(CO)3X.

KW - Atom transfer

KW - Electron transfer

KW - Halide exchange

KW - Kinetics

KW - Metal carbonyl anions

UR - https://www.scopus.com/pages/publications/1842491707

U2 - 10.1080/00958979608022700

DO - 10.1080/00958979608022700

M3 - Article

AN - SCOPUS:1842491707

SN - 0095-8972

VL - 38

SP - 145

EP - 149

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 1-2

ER -

Halide exchange reactions between CpW(CO)₃^- and CpMo(CO)₃X

Abstract

Keywords

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