Group- and Electron-Transfer Reactions of Tetracarbonylferrate(2−)

Yueqian Zhen; Jim D. Atwood

doi:10.1021/om00054a047

Group- and Electron-Transfer Reactions of Tetracarbonylferrate(2−)

Yueqian Zhen
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Reactions of Fe(CO)₄²⁻ with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO²⁺ transfer. Reaction with Mn₂(CO)₁₀ occurs by a single-electron transfer producing Fe₂(CO)₈²⁻ and Mn(CO)₅⁻. Reaction with Mn(CO)₆Br also occurs by a single-electron transfer. Reaction with Re(CO)₅Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.

Original language	English
Pages (from-to)	2778-2780
Number of pages	3
Journal	Organometallics
Volume	10
Issue number	8
DOIs	https://doi.org/10.1021/om00054a047
State	Published - Aug 1 1991

Access to Document

10.1021/om00054a047

Cite this

@article{22513e2c579147ae9374a0fab2c471c1,

title = "Group- and Electron-Transfer Reactions of Tetracarbonylferrate(2−)",

abstract = "Reactions of Fe(CO)42− with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO2+ transfer. Reaction with Mn2(CO)10 occurs by a single-electron transfer producing Fe2(CO)82− and Mn(CO)5−. Reaction with Mn(CO)6Br also occurs by a single-electron transfer. Reaction with Re(CO)5Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.",

author = "Yueqian Zhen and Atwood, \{Jim D.\}",

year = "1991",

month = aug,

day = "1",

doi = "10.1021/om00054a047",

language = "English",

volume = "10",

pages = "2778--2780",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Group- and Electron-Transfer Reactions of Tetracarbonylferrate(2−)

AU - Zhen, Yueqian

AU - Atwood, Jim D.

PY - 1991/8/1

Y1 - 1991/8/1

N2 - Reactions of Fe(CO)42− with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO2+ transfer. Reaction with Mn2(CO)10 occurs by a single-electron transfer producing Fe2(CO)82− and Mn(CO)5−. Reaction with Mn(CO)6Br also occurs by a single-electron transfer. Reaction with Re(CO)5Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.

AB - Reactions of Fe(CO)42− with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO2+ transfer. Reaction with Mn2(CO)10 occurs by a single-electron transfer producing Fe2(CO)82− and Mn(CO)5−. Reaction with Mn(CO)6Br also occurs by a single-electron transfer. Reaction with Re(CO)5Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.

UR - https://www.scopus.com/pages/publications/0000516658

U2 - 10.1021/om00054a047

DO - 10.1021/om00054a047

M3 - Article

AN - SCOPUS:0000516658

SN - 0276-7333

VL - 10

SP - 2778

EP - 2780

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Group- and Electron-Transfer Reactions of Tetracarbonylferrate(2−)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this