Graphene/graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O2 batteries

Qing Li; Ping Xu; Wei Gao; Shuguo Ma; Guoqi Zhang; Ruiguo Cao; Jaephil Cho; Hsing Lin Wang; Gang Wu

doi:10.1002/adma.201304218

Graphene/graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O₂ batteries

Qing Li
, Ping Xu
, Wei Gao
, Shuguo Ma
, Guoqi Zhang
, Ruiguo Cao
, Jaephil Cho
, Hsing Lin Wang
, Gang Wu

Department of Chemical and Biological Engineering

Los Alamos National Laboratory
Harbin Institute of Technology
University of South Carolina
City University of New York
Ulsan National Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

425 Scopus citations

Abstract

Nitrogen-doped graphene/graphene-tube nanocomposites are prepared by a hightemperature approach using a newly designed cage-containing metal-organic framework (MOF) to template nitrogen/carbon (dicyandiamide) and iron precursors. The resulting N-Fe-MOF catalysts universally exhibit high oxygen-reduction activity in acidic, alkaline, and non-aqueous electrolytes and superior cathode performance in Li-O₂ batteries.

Original language	English
Pages (from-to)	1378-1386
Number of pages	9
Journal	Advanced Materials
Volume	26
Issue number	9
DOIs	https://doi.org/10.1002/adma.201304218
State	Published - Mar 5 2014

Keywords

graphene
graphene tubes
lithium-oxygen batteries
metal-organic frameworks
oxygen reduction reaction

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10.1002/adma.201304218

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title = "Graphene/graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O2 batteries",

abstract = "Nitrogen-doped graphene/graphene-tube nanocomposites are prepared by a hightemperature approach using a newly designed cage-containing metal-organic framework (MOF) to template nitrogen/carbon (dicyandiamide) and iron precursors. The resulting N-Fe-MOF catalysts universally exhibit high oxygen-reduction activity in acidic, alkaline, and non-aqueous electrolytes and superior cathode performance in Li-O2 batteries.",

keywords = "graphene, graphene tubes, lithium-oxygen batteries, metal-organic frameworks, oxygen reduction reaction",

author = "Qing Li and Ping Xu and Wei Gao and Shuguo Ma and Guoqi Zhang and Ruiguo Cao and Jaephil Cho and Wang, \{Hsing Lin\} and Gang Wu",

year = "2014",

month = mar,

day = "5",

doi = "10.1002/adma.201304218",

language = "English",

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journal = "Advanced Materials",

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T1 - Graphene/graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O2 batteries

AU - Li, Qing

AU - Xu, Ping

AU - Gao, Wei

AU - Ma, Shuguo

AU - Zhang, Guoqi

AU - Cao, Ruiguo

AU - Cho, Jaephil

AU - Wang, Hsing Lin

AU - Wu, Gang

PY - 2014/3/5

Y1 - 2014/3/5

N2 - Nitrogen-doped graphene/graphene-tube nanocomposites are prepared by a hightemperature approach using a newly designed cage-containing metal-organic framework (MOF) to template nitrogen/carbon (dicyandiamide) and iron precursors. The resulting N-Fe-MOF catalysts universally exhibit high oxygen-reduction activity in acidic, alkaline, and non-aqueous electrolytes and superior cathode performance in Li-O2 batteries.

AB - Nitrogen-doped graphene/graphene-tube nanocomposites are prepared by a hightemperature approach using a newly designed cage-containing metal-organic framework (MOF) to template nitrogen/carbon (dicyandiamide) and iron precursors. The resulting N-Fe-MOF catalysts universally exhibit high oxygen-reduction activity in acidic, alkaline, and non-aqueous electrolytes and superior cathode performance in Li-O2 batteries.

KW - graphene

KW - graphene tubes

KW - lithium-oxygen batteries

KW - metal-organic frameworks

KW - oxygen reduction reaction

UR - https://www.scopus.com/pages/publications/84897614637

U2 - 10.1002/adma.201304218

DO - 10.1002/adma.201304218

M3 - Article

AN - SCOPUS:84897614637

SN - 0935-9648

VL - 26

SP - 1378

EP - 1386

JO - Advanced Materials

JF - Advanced Materials

IS - 9

ER -

Graphene/graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O₂ batteries

Abstract

Keywords

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