Geminal alkene-alkyne cross metathesis using a relay strategy

Joseph R. Clark; Jonathan M. French; Edgars Jecs; Steven T. Diver

doi:10.1021/ol301846q

Geminal alkene-alkyne cross metathesis using a relay strategy

Joseph R. Clark
, Jonathan M. French
, Edgars Jecs
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A relay strategy was employed to achieve an intermolecular ene-yne metathesis between 1,1-disubstituted alkenes and alkynes. The relay serves to activate an unreactive alkene which will not participate in ene-yne metathesis. The new relay cross ene-yne metathesis gives rise to 1,1,3-trisubstituted-1,3- dienes previously inaccessible by direct ene-yne metathesis methods.

Original language	English
Pages (from-to)	4178-4181
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	16
DOIs	https://doi.org/10.1021/ol301846q
State	Published - Aug 17 2012

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abstract = "A relay strategy was employed to achieve an intermolecular ene-yne metathesis between 1,1-disubstituted alkenes and alkynes. The relay serves to activate an unreactive alkene which will not participate in ene-yne metathesis. The new relay cross ene-yne metathesis gives rise to 1,1,3-trisubstituted-1,3- dienes previously inaccessible by direct ene-yne metathesis methods.",

author = "Clark, \{Joseph R.\} and French, \{Jonathan M.\} and Edgars Jecs and Diver, \{Steven T.\}",

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AU - Clark, Joseph R.

AU - French, Jonathan M.

AU - Jecs, Edgars

AU - Diver, Steven T.

PY - 2012/8/17

Y1 - 2012/8/17

N2 - A relay strategy was employed to achieve an intermolecular ene-yne metathesis between 1,1-disubstituted alkenes and alkynes. The relay serves to activate an unreactive alkene which will not participate in ene-yne metathesis. The new relay cross ene-yne metathesis gives rise to 1,1,3-trisubstituted-1,3- dienes previously inaccessible by direct ene-yne metathesis methods.

AB - A relay strategy was employed to achieve an intermolecular ene-yne metathesis between 1,1-disubstituted alkenes and alkynes. The relay serves to activate an unreactive alkene which will not participate in ene-yne metathesis. The new relay cross ene-yne metathesis gives rise to 1,1,3-trisubstituted-1,3- dienes previously inaccessible by direct ene-yne metathesis methods.

UR - https://www.scopus.com/pages/publications/84865254719

U2 - 10.1021/ol301846q

DO - 10.1021/ol301846q

M3 - Article

AN - SCOPUS:84865254719

SN - 1523-7060

VL - 14

SP - 4178

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JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

Geminal alkene-alkyne cross metathesis using a relay strategy

Abstract

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