Gas-phase ion-molecule chemistry of fullerene cations and dications with propene, 1-butene and isobutene

J. J. Stry; J. F. Garvey

doi:10.1021/j100085a005

Gas-phase ion-molecule chemistry of fullerene cations and dications with propene, 1-butene and isobutene

J. J. Stry
, J. F. Garvey

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The gas-phase ion-molecule reactions of C_n⁺ and C_n²⁺ (N = 54,56,60, and 70) with isobutene were investigated by utilizing a triple quadrupole mass spectrometer. In addition, the ion chemistry of C₆₀⁺ and C₆₀²⁺ with propene and 1-butene was investigated. The various ion-molecule reactions observed were highly dependent on the gas cell pressure and the collision energy of the primary ions. The product ions observed were governed primarily by associative and partial charge transfer reactions. The isomeric form of C₄H₈ as well as the size of the fullerene ion affected the reactions observed. For example, 1-butene readily adds to C₆₀²⁺, while isobutene adducts were not detected. Also, fullerene cations with adjacent five-membered rings (n = 54, 56 and 58) react with isobutene to produce C_n(C₄H₈)⁺ while C₆₀²⁺ and C₇₀²⁺ do not.

Original language	English
Pages (from-to)	8289-8294
Number of pages	6
Journal	Journal of Physical Chemistry
Volume	98
Issue number	34
DOIs	https://doi.org/10.1021/j100085a005
State	Published - 1994

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@article{e193cde68a5a4237a649cdd37f47f2bf,

title = "Gas-phase ion-molecule chemistry of fullerene cations and dications with propene, 1-butene and isobutene",

abstract = "The gas-phase ion-molecule reactions of Cn+ and Cn2+ (N = 54,56,60, and 70) with isobutene were investigated by utilizing a triple quadrupole mass spectrometer. In addition, the ion chemistry of C60+ and C602+ with propene and 1-butene was investigated. The various ion-molecule reactions observed were highly dependent on the gas cell pressure and the collision energy of the primary ions. The product ions observed were governed primarily by associative and partial charge transfer reactions. The isomeric form of C4H8 as well as the size of the fullerene ion affected the reactions observed. For example, 1-butene readily adds to C602+, while isobutene adducts were not detected. Also, fullerene cations with adjacent five-membered rings (n = 54, 56 and 58) react with isobutene to produce Cn(C4H8)+ while C602+ and C702+ do not.",

author = "Stry, \{J. J.\} and Garvey, \{J. F.\}",

year = "1994",

doi = "10.1021/j100085a005",

language = "English",

volume = "98",

pages = "8289--8294",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "34",

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TY - JOUR

T1 - Gas-phase ion-molecule chemistry of fullerene cations and dications with propene, 1-butene and isobutene

AU - Stry, J. J.

AU - Garvey, J. F.

PY - 1994

Y1 - 1994

N2 - The gas-phase ion-molecule reactions of Cn+ and Cn2+ (N = 54,56,60, and 70) with isobutene were investigated by utilizing a triple quadrupole mass spectrometer. In addition, the ion chemistry of C60+ and C602+ with propene and 1-butene was investigated. The various ion-molecule reactions observed were highly dependent on the gas cell pressure and the collision energy of the primary ions. The product ions observed were governed primarily by associative and partial charge transfer reactions. The isomeric form of C4H8 as well as the size of the fullerene ion affected the reactions observed. For example, 1-butene readily adds to C602+, while isobutene adducts were not detected. Also, fullerene cations with adjacent five-membered rings (n = 54, 56 and 58) react with isobutene to produce Cn(C4H8)+ while C602+ and C702+ do not.

AB - The gas-phase ion-molecule reactions of Cn+ and Cn2+ (N = 54,56,60, and 70) with isobutene were investigated by utilizing a triple quadrupole mass spectrometer. In addition, the ion chemistry of C60+ and C602+ with propene and 1-butene was investigated. The various ion-molecule reactions observed were highly dependent on the gas cell pressure and the collision energy of the primary ions. The product ions observed were governed primarily by associative and partial charge transfer reactions. The isomeric form of C4H8 as well as the size of the fullerene ion affected the reactions observed. For example, 1-butene readily adds to C602+, while isobutene adducts were not detected. Also, fullerene cations with adjacent five-membered rings (n = 54, 56 and 58) react with isobutene to produce Cn(C4H8)+ while C602+ and C702+ do not.

UR - https://www.scopus.com/pages/publications/0028494211

U2 - 10.1021/j100085a005

DO - 10.1021/j100085a005

M3 - Article

AN - SCOPUS:0028494211

SN - 0022-3654

VL - 98

SP - 8289

EP - 8294

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 34

ER -

Gas-phase ion-molecule chemistry of fullerene cations and dications with propene, 1-butene and isobutene

Abstract

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