Fragmentation of Fe(CO)5ROH (R CH3 and C2H5) heteroclusters induced by 248 nm multiphoton ionization

M. Y.M. Lyktey; P. Xia; J. F. Garvey

doi:10.1016/0009-2614(95)00371-1

Fragmentation of Fe(CO)₅ROH (R CH₃ and C₂H₅) heteroclusters induced by 248 nm multiphoton ionization

M. Y.M. Lyktey
, P. Xia
, J. F. Garvey

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The ionic fragmentation of Fe(CO)₅ within an environment of methanol or ethanol clusters was studied. Reflectron-time-of-flight mass spectrometry was employed to analyze the mixed cluster ions generated by 248 nm multiphoton ionization of [Fe(CO)₅][ROH]_{n = 1 - 20} clusters (R CH₃ or C₂H₅). The fragmentation patterns were found to be quite different from those observed in the gas and condensed phases. A mechanism for the fragmentation of alcohol cluster solvated metal carbonyls is proposed, which is consistent with previous studies in this area.

Original language	English
Pages (from-to)	54-60
Number of pages	7
Journal	Chemical Physics Letters
Volume	238
Issue number	1-3
DOIs	https://doi.org/10.1016/0009-2614(95)00371-1
State	Published - May 26 1995

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title = "Fragmentation of Fe(CO)5ROH (R CH3 and C2H5) heteroclusters induced by 248 nm multiphoton ionization",

abstract = "The ionic fragmentation of Fe(CO)5 within an environment of methanol or ethanol clusters was studied. Reflectron-time-of-flight mass spectrometry was employed to analyze the mixed cluster ions generated by 248 nm multiphoton ionization of [Fe(CO)5][ROH]n = 1 - 20 clusters (R CH3 or C2H5). The fragmentation patterns were found to be quite different from those observed in the gas and condensed phases. A mechanism for the fragmentation of alcohol cluster solvated metal carbonyls is proposed, which is consistent with previous studies in this area.",

author = "Lyktey, \{M. Y.M.\} and P. Xia and Garvey, \{J. F.\}",

year = "1995",

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doi = "10.1016/0009-2614(95)00371-1",

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journal = "Chemical Physics Letters",

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T1 - Fragmentation of Fe(CO)5ROH (R CH3 and C2H5) heteroclusters induced by 248 nm multiphoton ionization

AU - Lyktey, M. Y.M.

AU - Xia, P.

AU - Garvey, J. F.

PY - 1995/5/26

Y1 - 1995/5/26

N2 - The ionic fragmentation of Fe(CO)5 within an environment of methanol or ethanol clusters was studied. Reflectron-time-of-flight mass spectrometry was employed to analyze the mixed cluster ions generated by 248 nm multiphoton ionization of [Fe(CO)5][ROH]n = 1 - 20 clusters (R CH3 or C2H5). The fragmentation patterns were found to be quite different from those observed in the gas and condensed phases. A mechanism for the fragmentation of alcohol cluster solvated metal carbonyls is proposed, which is consistent with previous studies in this area.

AB - The ionic fragmentation of Fe(CO)5 within an environment of methanol or ethanol clusters was studied. Reflectron-time-of-flight mass spectrometry was employed to analyze the mixed cluster ions generated by 248 nm multiphoton ionization of [Fe(CO)5][ROH]n = 1 - 20 clusters (R CH3 or C2H5). The fragmentation patterns were found to be quite different from those observed in the gas and condensed phases. A mechanism for the fragmentation of alcohol cluster solvated metal carbonyls is proposed, which is consistent with previous studies in this area.

UR - https://www.scopus.com/pages/publications/0042686238

U2 - 10.1016/0009-2614(95)00371-1

DO - 10.1016/0009-2614(95)00371-1

M3 - Article

AN - SCOPUS:0042686238

SN - 0009-2614

VL - 238

SP - 54

EP - 60

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Fragmentation of Fe(CO)₅ROH (R CH₃ and C₂H₅) heteroclusters induced by 248 nm multiphoton ionization

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