Formation of [3]catenanes from 10 precursors via multicomponent coordination-driven self-assembly of metallarectangles

Shijun Li; Jianying Huang; Timothy R. Cook; J. Bryant Pollock; Hyunuk Kim; Ki Whan Chi; Peter J. Stang

doi:10.1021/ja3118812

Formation of [3]catenanes from 10 precursors via multicomponent coordination-driven self-assembly of metallarectangles

Shijun Li
, Jianying Huang
, Timothy R. Cook
, J. Bryant Pollock
, Hyunuk Kim
, Ki Whan Chi
, Peter J. Stang

Chemistry

Hangzhou Normal University
University of Utah
Zhejiang Gongshang University
Korea Institute of Energy Research
University of Ulsan

Research output: Contribution to journal › Article › peer-review

173 Scopus citations

Abstract

We describe the formation of a suite of [3]catenanes via multicomponent coordination-driven self-assembly and host-guest complexation of a rectangular scaffold comprising a 90 Pt-based acceptor building block with a pseudorotaxane bis(pyridinium)ethane/dibenzo-24-crown-8 linear dipyridyl ligand and three dicarboxylate donors. The doubly threaded [3]catenanes are formed from a total of 10 molecular components from four unique species. Furthermore, the dynamic catenation process is reversible and can be switched off and on in a controllable manner by successive addition of KPF₆ and 18-crown-6, as monitored by ¹H and ³¹P NMR spectroscopy.

Original language	English
Pages (from-to)	2084-2087
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	6
DOIs	https://doi.org/10.1021/ja3118812
State	Published - Feb 13 2013

Access to Document

10.1021/ja3118812

Cite this

@article{b8c513fc4bd64b528de2aa6d77d30ce3,

title = "Formation of [3]catenanes from 10 precursors via multicomponent coordination-driven self-assembly of metallarectangles",

abstract = "We describe the formation of a suite of [3]catenanes via multicomponent coordination-driven self-assembly and host-guest complexation of a rectangular scaffold comprising a 90 Pt-based acceptor building block with a pseudorotaxane bis(pyridinium)ethane/dibenzo-24-crown-8 linear dipyridyl ligand and three dicarboxylate donors. The doubly threaded [3]catenanes are formed from a total of 10 molecular components from four unique species. Furthermore, the dynamic catenation process is reversible and can be switched off and on in a controllable manner by successive addition of KPF6 and 18-crown-6, as monitored by 1H and 31P NMR spectroscopy.",

author = "Shijun Li and Jianying Huang and Cook, \{Timothy R.\} and Pollock, \{J. Bryant\} and Hyunuk Kim and Chi, \{Ki Whan\} and Stang, \{Peter J.\}",

year = "2013",

month = feb,

day = "13",

doi = "10.1021/ja3118812",

language = "English",

volume = "135",

pages = "2084--2087",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Formation of [3]catenanes from 10 precursors via multicomponent coordination-driven self-assembly of metallarectangles

AU - Li, Shijun

AU - Huang, Jianying

AU - Cook, Timothy R.

AU - Pollock, J. Bryant

AU - Kim, Hyunuk

AU - Chi, Ki Whan

AU - Stang, Peter J.

PY - 2013/2/13

Y1 - 2013/2/13

N2 - We describe the formation of a suite of [3]catenanes via multicomponent coordination-driven self-assembly and host-guest complexation of a rectangular scaffold comprising a 90 Pt-based acceptor building block with a pseudorotaxane bis(pyridinium)ethane/dibenzo-24-crown-8 linear dipyridyl ligand and three dicarboxylate donors. The doubly threaded [3]catenanes are formed from a total of 10 molecular components from four unique species. Furthermore, the dynamic catenation process is reversible and can be switched off and on in a controllable manner by successive addition of KPF6 and 18-crown-6, as monitored by 1H and 31P NMR spectroscopy.

AB - We describe the formation of a suite of [3]catenanes via multicomponent coordination-driven self-assembly and host-guest complexation of a rectangular scaffold comprising a 90 Pt-based acceptor building block with a pseudorotaxane bis(pyridinium)ethane/dibenzo-24-crown-8 linear dipyridyl ligand and three dicarboxylate donors. The doubly threaded [3]catenanes are formed from a total of 10 molecular components from four unique species. Furthermore, the dynamic catenation process is reversible and can be switched off and on in a controllable manner by successive addition of KPF6 and 18-crown-6, as monitored by 1H and 31P NMR spectroscopy.

UR - https://www.scopus.com/pages/publications/84873687266

U2 - 10.1021/ja3118812

DO - 10.1021/ja3118812

M3 - Article

AN - SCOPUS:84873687266

SN - 0002-7863

VL - 135

SP - 2084

EP - 2087

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 6

ER -

Formation of [3]catenanes from 10 precursors via multicomponent coordination-driven self-assembly of metallarectangles

Abstract

Access to Document

Other files and links

Fingerprint

Cite this