Fluxional behavior of the bridging vinyl group in HOs3(CO)10(CHCH2) and related complexes

J. R. Shapley; S. I. Richter; M. Tachikawa; J. B. Keister

doi:10.1016/S0022-328X(00)86960-0

Fluxional behavior of the bridging vinyl group in HOs₃(CO)₁₀(CHCH₂) and related complexes

J. R. Shapley
, S. I. Richter
, M. Tachikawa
, J. B. Keister

Chemistry

University of Illinois at Urbana-Champaign

Research output: Contribution to journal › Article › peer-review

135 Scopus citations

Abstract

¹³C NMR spectra of the cluster complexes HOs₃(CO)₁₀(CH=CHR) establish that the σ and π bonds binding the bridging vinylic group are rapidly interchanged between the bridged osmium atoms.

Original language	English
Pages (from-to)	C43-C46
Journal	Journal of Organometallic Chemistry
Volume	94
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)86960-0
State	Published - Aug 5 1975

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@article{b5bef897bcc44ac487dff978772e8e27,

title = "Fluxional behavior of the bridging vinyl group in HOs3(CO)10(CHCH2) and related complexes",

abstract = "13C NMR spectra of the cluster complexes HOs3(CO)10(CH=CHR) establish that the σ and π bonds binding the bridging vinylic group are rapidly interchanged between the bridged osmium atoms.",

author = "Shapley, \{J. R.\} and Richter, \{S. I.\} and M. Tachikawa and Keister, \{J. B.\}",

year = "1975",

month = aug,

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doi = "10.1016/S0022-328X(00)86960-0",

language = "English",

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pages = "C43--C46",

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T1 - Fluxional behavior of the bridging vinyl group in HOs3(CO)10(CHCH2) and related complexes

AU - Shapley, J. R.

AU - Richter, S. I.

AU - Tachikawa, M.

AU - Keister, J. B.

PY - 1975/8/5

Y1 - 1975/8/5

N2 - 13C NMR spectra of the cluster complexes HOs3(CO)10(CH=CHR) establish that the σ and π bonds binding the bridging vinylic group are rapidly interchanged between the bridged osmium atoms.

AB - 13C NMR spectra of the cluster complexes HOs3(CO)10(CH=CHR) establish that the σ and π bonds binding the bridging vinylic group are rapidly interchanged between the bridged osmium atoms.

UR - https://www.scopus.com/pages/publications/0002920037

U2 - 10.1016/S0022-328X(00)86960-0

DO - 10.1016/S0022-328X(00)86960-0

M3 - Article

AN - SCOPUS:0002920037

SN - 0022-328X

VL - 94

SP - C43-C46

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Fluxional behavior of the bridging vinyl group in HOs₃(CO)₁₀(CHCH₂) and related complexes

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