Expanded scope in ethylene-alkyne cross-metathesis: Coordinating heteroatom functionality at the propargylic position

Jason A. Smulik; Steven T. Diver

doi:10.1021/ol006035l

Expanded scope in ethylene-alkyne cross-metathesis: Coordinating heteroatom functionality at the propargylic position

Jason A. Smulik
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

120 Scopus citations

Abstract

(equation presented) The Grubbs 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium complex 1 catalyzed ethylene-alkyne cross-metathesis and was shown to tolerate free hydroxyl groups and coordinating functionality at the propargylic and homopropargylic positions. Hindered and enantiomerically enriched 1-substituted alkynes also react efficiently under the reported conditions.

Original language	English
Pages (from-to)	2271-2274
Number of pages	4
Journal	Organic Letters
Volume	2
Issue number	15
DOIs	https://doi.org/10.1021/ol006035l
State	Published - Jul 27 2000

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title = "Expanded scope in ethylene-alkyne cross-metathesis: Coordinating heteroatom functionality at the propargylic position",

abstract = "(equation presented) The Grubbs 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium complex 1 catalyzed ethylene-alkyne cross-metathesis and was shown to tolerate free hydroxyl groups and coordinating functionality at the propargylic and homopropargylic positions. Hindered and enantiomerically enriched 1-substituted alkynes also react efficiently under the reported conditions.",

author = "Smulik, \{Jason A.\} and Diver, \{Steven T.\}",

year = "2000",

month = jul,

day = "27",

doi = "10.1021/ol006035l",

language = "English",

volume = "2",

pages = "2271--2274",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Expanded scope in ethylene-alkyne cross-metathesis

T2 - Coordinating heteroatom functionality at the propargylic position

AU - Smulik, Jason A.

AU - Diver, Steven T.

PY - 2000/7/27

Y1 - 2000/7/27

N2 - (equation presented) The Grubbs 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium complex 1 catalyzed ethylene-alkyne cross-metathesis and was shown to tolerate free hydroxyl groups and coordinating functionality at the propargylic and homopropargylic positions. Hindered and enantiomerically enriched 1-substituted alkynes also react efficiently under the reported conditions.

AB - (equation presented) The Grubbs 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium complex 1 catalyzed ethylene-alkyne cross-metathesis and was shown to tolerate free hydroxyl groups and coordinating functionality at the propargylic and homopropargylic positions. Hindered and enantiomerically enriched 1-substituted alkynes also react efficiently under the reported conditions.

UR - https://www.scopus.com/pages/publications/0034720907

U2 - 10.1021/ol006035l

DO - 10.1021/ol006035l

M3 - Article

C2 - 10930261

AN - SCOPUS:0034720907

SN - 1523-7060

VL - 2

SP - 2271

EP - 2274

JO - Organic Letters

JF - Organic Letters

IS - 15

ER -

Expanded scope in ethylene-alkyne cross-metathesis: Coordinating heteroatom functionality at the propargylic position

Abstract

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