Evolution of copper(II) as a new alkene amination promoter and catalyst

Sherry R. Chemler

doi:10.1016/j.jorganchem.2010.08.041

Evolution of copper(II) as a new alkene amination promoter and catalyst

Sherry R. Chemler

Chemistry

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

Copper(II) carboxylates and chiral copper(II) triflate· bis(oxazoline) complexes promote and catalyze intramolecular alkene carboamination, diamination and aminooxygenation reactions, creating an array of nitrogen heterocycles. High diastereoselectivity and enantioselectivity can be achieved in these transformations. This account reviews the discovery and development of these useful and interesting reactions.

Original language	English
Pages (from-to)	150-158
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2010.08.041
State	Published - Jan 1 2011

Keywords

Alkene
Aminooxygenation
Carboamination
Copper
Diamination
Enantioselective

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10.1016/j.jorganchem.2010.08.041

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abstract = "Copper(II) carboxylates and chiral copper(II) triflate· bis(oxazoline) complexes promote and catalyze intramolecular alkene carboamination, diamination and aminooxygenation reactions, creating an array of nitrogen heterocycles. High diastereoselectivity and enantioselectivity can be achieved in these transformations. This account reviews the discovery and development of these useful and interesting reactions.",

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AB - Copper(II) carboxylates and chiral copper(II) triflate· bis(oxazoline) complexes promote and catalyze intramolecular alkene carboamination, diamination and aminooxygenation reactions, creating an array of nitrogen heterocycles. High diastereoselectivity and enantioselectivity can be achieved in these transformations. This account reviews the discovery and development of these useful and interesting reactions.

KW - Alkene

KW - Aminooxygenation

KW - Carboamination

KW - Copper

KW - Diamination

KW - Enantioselective

UR - https://www.scopus.com/pages/publications/78649902157

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DO - 10.1016/j.jorganchem.2010.08.041

M3 - Article

AN - SCOPUS:78649902157

SN - 0022-328X

VL - 696

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EP - 158

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Evolution of copper(II) as a new alkene amination promoter and catalyst

Abstract

Keywords

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