Evidence for C-O Bond Formation, Aldehyde Decarbonylation, and Dimerization by Reaction of Formaldehyde and Acetaldehyde with traws-ROIr(CO)(PPh3)2

Karen A. Bernard; Jim D. Atwood

doi:10.1021/om00091a037

Evidence for C-O Bond Formation, Aldehyde Decarbonylation, and Dimerization by Reaction of Formaldehyde and Acetaldehyde with traws-ROIr(CO)(PPh₃)₂

Karen A. Bernard
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The reaction of formaldehyde and acet- aldehyde with trans-ROIr(CO)(PPh₃)₂(R = Me, i-Pr, n-Pr, t-Bu) leads to formation of esters ROC(O)R' (R' = H or Me) by formation of a carbon-oxygen bond between the alkoxide and the acyl from the aldehyde and to catalytic production of the ester R'CH₂C(O)OR' in a Tischenko reaction.

Original language	English
Pages (from-to)	235-236
Number of pages	2
Journal	Organometallics
Volume	7
Issue number	1
DOIs	https://doi.org/10.1021/om00091a037
State	Published - Jan 1 1988

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abstract = "The reaction of formaldehyde and acet- aldehyde with trans-ROIr(CO)(PPh3)2(R = Me, i-Pr, n-Pr, t-Bu) leads to formation of esters ROC(O)R' (R' = H or Me) by formation of a carbon-oxygen bond between the alkoxide and the acyl from the aldehyde and to catalytic production of the ester R'CH2C(O)OR' in a Tischenko reaction.",

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AU - Bernard, Karen A.

AU - Atwood, Jim D.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The reaction of formaldehyde and acet- aldehyde with trans-ROIr(CO)(PPh3)2(R = Me, i-Pr, n-Pr, t-Bu) leads to formation of esters ROC(O)R' (R' = H or Me) by formation of a carbon-oxygen bond between the alkoxide and the acyl from the aldehyde and to catalytic production of the ester R'CH2C(O)OR' in a Tischenko reaction.

AB - The reaction of formaldehyde and acet- aldehyde with trans-ROIr(CO)(PPh3)2(R = Me, i-Pr, n-Pr, t-Bu) leads to formation of esters ROC(O)R' (R' = H or Me) by formation of a carbon-oxygen bond between the alkoxide and the acyl from the aldehyde and to catalytic production of the ester R'CH2C(O)OR' in a Tischenko reaction.

UR - https://www.scopus.com/pages/publications/0003516295

U2 - 10.1021/om00091a037

DO - 10.1021/om00091a037

M3 - Article

AN - SCOPUS:0003516295

SN - 0276-7333

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IS - 1

ER -

Evidence for C-O Bond Formation, Aldehyde Decarbonylation, and Dimerization by Reaction of Formaldehyde and Acetaldehyde with traws-ROIr(CO)(PPh₃)₂

Abstract

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