Ethylene-Promoted Intermolecular Enyne Metathesis

Anthony J. Giessert; Nicholas J. Brazis; Steven T. Diver

doi:10.1021/ol035270b

Ethylene-Promoted Intermolecular Enyne Metathesis

Anthony J. Giessert
, Nicholas J. Brazis
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

(Matrix presented) Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing.

Original language	English
Pages (from-to)	3819-3822
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	21
DOIs	https://doi.org/10.1021/ol035270b
State	Published - Oct 16 2003

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@article{d671587d7ef44e508c5dff50a455c569,

title = "Ethylene-Promoted Intermolecular Enyne Metathesis",

abstract = "(Matrix presented) Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing.",

author = "Giessert, \{Anthony J.\} and Brazis, \{Nicholas J.\} and Diver, \{Steven T.\}",

year = "2003",

month = oct,

day = "16",

doi = "10.1021/ol035270b",

language = "English",

volume = "5",

pages = "3819--3822",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Ethylene-Promoted Intermolecular Enyne Metathesis

AU - Giessert, Anthony J.

AU - Brazis, Nicholas J.

AU - Diver, Steven T.

PY - 2003/10/16

Y1 - 2003/10/16

N2 - (Matrix presented) Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing.

AB - (Matrix presented) Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing.

UR - https://www.scopus.com/pages/publications/0242460343

U2 - 10.1021/ol035270b

DO - 10.1021/ol035270b

M3 - Article

C2 - 14535718

AN - SCOPUS:0242460343

SN - 1523-7060

VL - 5

SP - 3819

EP - 3822

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Ethylene-Promoted Intermolecular Enyne Metathesis

Abstract

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