Ethylene metathesis of sulfur-containing alkynes

Jason A. Smulik; Anthony J. Giessert; Steven T. Diver

doi:10.1016/S0040-4039(01)02098-6

Ethylene metathesis of sulfur-containing alkynes

Jason A. Smulik
, Anthony J. Giessert
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Enyne metathesis of sulfur-containing alkynes and ethylene has been achieved. High yields were obtained by use of thiol esters in the alkyne partner for the cross metathesis with ethylene. The necessary reactivity and functional group compatibility were achieved through the use of the Grubbs' second generation benzylidene carbene catalyst.

Original language	English
Pages (from-to)	209-211
Number of pages	3
Journal	Tetrahedron Letters
Volume	43
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(01)02098-6
State	Published - Jan 7 2002

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title = "Ethylene metathesis of sulfur-containing alkynes",

abstract = "Enyne metathesis of sulfur-containing alkynes and ethylene has been achieved. High yields were obtained by use of thiol esters in the alkyne partner for the cross metathesis with ethylene. The necessary reactivity and functional group compatibility were achieved through the use of the Grubbs' second generation benzylidene carbene catalyst.",

author = "Smulik, \{Jason A.\} and Giessert, \{Anthony J.\} and Diver, \{Steven T.\}",

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T1 - Ethylene metathesis of sulfur-containing alkynes

AU - Smulik, Jason A.

AU - Giessert, Anthony J.

AU - Diver, Steven T.

PY - 2002/1/7

Y1 - 2002/1/7

N2 - Enyne metathesis of sulfur-containing alkynes and ethylene has been achieved. High yields were obtained by use of thiol esters in the alkyne partner for the cross metathesis with ethylene. The necessary reactivity and functional group compatibility were achieved through the use of the Grubbs' second generation benzylidene carbene catalyst.

AB - Enyne metathesis of sulfur-containing alkynes and ethylene has been achieved. High yields were obtained by use of thiol esters in the alkyne partner for the cross metathesis with ethylene. The necessary reactivity and functional group compatibility were achieved through the use of the Grubbs' second generation benzylidene carbene catalyst.

UR - https://www.scopus.com/pages/publications/0037033234

U2 - 10.1016/S0040-4039(01)02098-6

DO - 10.1016/S0040-4039(01)02098-6

M3 - Article

AN - SCOPUS:0037033234

SN - 0040-4039

VL - 43

SP - 209

EP - 211

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 2

ER -

Ethylene metathesis of sulfur-containing alkynes

Abstract

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