Energy transfer from a polymer host to a europium complex in light-emitting diodes

Energy transfer leading to electroluminescence of a lanthanide complex, Eu(Fod)₃MK (Fod = heptafluoro-dimethyl-octanedionate, MK = 4, 4′-bis(N,N-dimethylarninobenzophenone) doped into PVK host is investigated. The optical properties of pure Eu(Fod)₃MK and its doping in PVK show that the PVK host can efficiently transfer energy to europium ions through a co-ligand of MK due to good spectrally overlap. Light-emitting diodes (LED) consisting of PVK doped with 1-5 wt% of Eu(Fod) ₃MK also demonstrates this energy transfer. Organolanthanide complexes doped into a wide-gap conducting polymers would lead to efficient and pure red organic LEDs to solve the full colour conjugated polymer displays.