Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Nora Hellou; Claire Jahier-Diallo; Olivier Baslé; Monika Srebro-Hooper; Loïc Toupet; Thierry Roisnel; Elsa Caytan; Christian Roussel; Nicolas Vanthuyne; Jochen Autschbach; Marc Mauduit; Jeanne Crassous

doi:10.1039/c6cc04257k

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Nora Hellou
, Claire Jahier-Diallo
, Olivier Baslé
, Monika Srebro-Hooper
, Loïc Toupet
, Thierry Roisnel
, Elsa Caytan
, Christian Roussel
, Nicolas Vanthuyne
, Jochen Autschbach
, Marc Mauduit
, Jeanne Crassous

Chemistry

Institut des Sciences Chimiques de Rennes
Université de Rennes
Jagiellonian University in Kraków
Aix Marseille University

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.

Original language	English
Pages (from-to)	9243-9246
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	59
DOIs	https://doi.org/10.1039/c6cc04257k
State	Published - 2016

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10.1039/c6cc04257k

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title = "Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands",

abstract = "The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.",

author = "Nora Hellou and Claire Jahier-Diallo and Olivier Basl{\'e} and Monika Srebro-Hooper and Lo{\"i}c Toupet and Thierry Roisnel and Elsa Caytan and Christian Roussel and Nicolas Vanthuyne and Jochen Autschbach and Marc Mauduit and Jeanne Crassous",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc04257k",

language = "English",

volume = "52",

pages = "9243--9246",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "59",

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TY - JOUR

T1 - Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

AU - Hellou, Nora

AU - Jahier-Diallo, Claire

AU - Baslé, Olivier

AU - Srebro-Hooper, Monika

AU - Toupet, Loïc

AU - Roisnel, Thierry

AU - Caytan, Elsa

AU - Roussel, Christian

AU - Vanthuyne, Nicolas

AU - Autschbach, Jochen

AU - Mauduit, Marc

AU - Crassous, Jeanne

PY - 2016

Y1 - 2016

N2 - The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.

AB - The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.

UR - https://www.scopus.com/pages/publications/84978698393

U2 - 10.1039/c6cc04257k

DO - 10.1039/c6cc04257k

M3 - Article

AN - SCOPUS:84978698393

SN - 1359-7345

VL - 52

SP - 9243

EP - 9246

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Abstract

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