Electron Transfer between Metal Cluster Complexes: Reaction of the Dianlons M3(CO)112− with the Dodecacarbonyltrimetal Clusters M3(CO)12 (M = Fe, Ru, Os)

M. Shauna Corraine; Jim D. Atwood

doi:10.1021/om00054a084

Electron Transfer between Metal Cluster Complexes: Reaction of the Dianlons M₃(CO)₁₁²⁻ with the Dodecacarbonyltrimetal Clusters M₃(CO)₁₂ (M = Fe, Ru, Os)

M. Shauna Corraine
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Electron-transfer reactions between trinuclear dianions M₃(CO)₁₁²⁻ and neutral clusters M′₃(CO)₁₂ occur for M = Os, M′ = Fe and Ru and for M = Ru, M′ = Fe, producing the new clusters and cluster dianions M′₃− (CO)₁₁²⁻ and M₃(CO)₁₂. The reactions are consistent with the two-electron potentials obtained from reactions of the clusters with mononuclear anions. Isotopic labeling is inconsistent with a CO²⁺ transfer and indicates an outer-sphere electron-transfer mechanism through odd-electron intermediates.

Original language	English
Pages (from-to)	2985-2986
Number of pages	2
Journal	Organometallics
Volume	10
Issue number	8
DOIs	https://doi.org/10.1021/om00054a084
State	Published - Aug 1 1991

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title = "Electron Transfer between Metal Cluster Complexes: Reaction of the Dianlons M3(CO)112− with the Dodecacarbonyltrimetal Clusters M3(CO)12 (M = Fe, Ru, Os)",

abstract = "Electron-transfer reactions between trinuclear dianions M3(CO)112− and neutral clusters M′3(CO)12 occur for M = Os, M′ = Fe and Ru and for M = Ru, M′ = Fe, producing the new clusters and cluster dianions M′3− (CO)112− and M3(CO)12. The reactions are consistent with the two-electron potentials obtained from reactions of the clusters with mononuclear anions. Isotopic labeling is inconsistent with a CO2+ transfer and indicates an outer-sphere electron-transfer mechanism through odd-electron intermediates.",

author = "\{Shauna Corraine\}, M. and Atwood, \{Jim D.\}",

year = "1991",

month = aug,

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doi = "10.1021/om00054a084",

language = "English",

volume = "10",

pages = "2985--2986",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Electron Transfer between Metal Cluster Complexes

T2 - Reaction of the Dianlons M3(CO)112− with the Dodecacarbonyltrimetal Clusters M3(CO)12 (M = Fe, Ru, Os)

AU - Shauna Corraine, M.

AU - Atwood, Jim D.

PY - 1991/8/1

Y1 - 1991/8/1

N2 - Electron-transfer reactions between trinuclear dianions M3(CO)112− and neutral clusters M′3(CO)12 occur for M = Os, M′ = Fe and Ru and for M = Ru, M′ = Fe, producing the new clusters and cluster dianions M′3− (CO)112− and M3(CO)12. The reactions are consistent with the two-electron potentials obtained from reactions of the clusters with mononuclear anions. Isotopic labeling is inconsistent with a CO2+ transfer and indicates an outer-sphere electron-transfer mechanism through odd-electron intermediates.

AB - Electron-transfer reactions between trinuclear dianions M3(CO)112− and neutral clusters M′3(CO)12 occur for M = Os, M′ = Fe and Ru and for M = Ru, M′ = Fe, producing the new clusters and cluster dianions M′3− (CO)112− and M3(CO)12. The reactions are consistent with the two-electron potentials obtained from reactions of the clusters with mononuclear anions. Isotopic labeling is inconsistent with a CO2+ transfer and indicates an outer-sphere electron-transfer mechanism through odd-electron intermediates.

UR - https://www.scopus.com/pages/publications/33751500429

U2 - 10.1021/om00054a084

DO - 10.1021/om00054a084

M3 - Article

AN - SCOPUS:33751500429

SN - 0276-7333

VL - 10

SP - 2985

EP - 2986

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Electron Transfer between Metal Cluster Complexes: Reaction of the Dianlons M₃(CO)₁₁²⁻ with the Dodecacarbonyltrimetal Clusters M₃(CO)₁₂ (M = Fe, Ru, Os)

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