Electrochemical quartz crystal microbalance studies of redox polymer films

A. Robert Hillman; David C. Loveday; Andrew Glidle; Johannes G. Vos; Alan P. Clarke; David Kelly; Stanley Bruckenstein

doi:10.1002/masy.19940800122

Electrochemical quartz crystal microbalance studies of redox polymer films

A. Robert Hillman
, David C. Loveday
, Andrew Glidle
, Johannes G. Vos
, Alan P. Clarke
, David Kelly
, Stanley Bruckenstein

Chemistry

University of Leicester
University of Glasgow
Dublin City University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Electrochemical quartz crystal microbalance measurements are reported for redox switching of thin films of three macromolecule‐metal complexes: poly(vinylferrocene) (PVF), 10% osmium‐functionalized poly(vinylpyridine) (Os‐PVP), and 10% osmium functionalized poly(vinylpyridine‐co‐styrene) (Os‐PVP‐co‐PS). The data provide insight into the ion and solvent transfer processes associated with electron transfer between the electrode and the electroactive film. Four important parameters are identified: electrolyte composition, (co)polymer composition, prior film history and experimental time scale.

Original language	English
Pages (from-to)	323-335
Number of pages	13
Journal	Macromolecular Symposia
Volume	80
Issue number	1
DOIs	https://doi.org/10.1002/masy.19940800122
State	Published - Mar 1994

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title = "Electrochemical quartz crystal microbalance studies of redox polymer films",

abstract = "Electrochemical quartz crystal microbalance measurements are reported for redox switching of thin films of three macromolecule‐metal complexes: poly(vinylferrocene) (PVF), 10\% osmium‐functionalized poly(vinylpyridine) (Os‐PVP), and 10\% osmium functionalized poly(vinylpyridine‐co‐styrene) (Os‐PVP‐co‐PS). The data provide insight into the ion and solvent transfer processes associated with electron transfer between the electrode and the electroactive film. Four important parameters are identified: electrolyte composition, (co)polymer composition, prior film history and experimental time scale.",

author = "\{Robert Hillman\}, A. and Loveday, \{David C.\} and Andrew Glidle and Vos, \{Johannes G.\} and Clarke, \{Alan P.\} and David Kelly and Stanley Bruckenstein",

year = "1994",

month = mar,

doi = "10.1002/masy.19940800122",

language = "English",

volume = "80",

pages = "323--335",

journal = "Macromolecular Symposia",

issn = "1022-1360",

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TY - JOUR

T1 - Electrochemical quartz crystal microbalance studies of redox polymer films

AU - Robert Hillman, A.

AU - Loveday, David C.

AU - Glidle, Andrew

AU - Vos, Johannes G.

AU - Clarke, Alan P.

AU - Kelly, David

AU - Bruckenstein, Stanley

PY - 1994/3

Y1 - 1994/3

N2 - Electrochemical quartz crystal microbalance measurements are reported for redox switching of thin films of three macromolecule‐metal complexes: poly(vinylferrocene) (PVF), 10% osmium‐functionalized poly(vinylpyridine) (Os‐PVP), and 10% osmium functionalized poly(vinylpyridine‐co‐styrene) (Os‐PVP‐co‐PS). The data provide insight into the ion and solvent transfer processes associated with electron transfer between the electrode and the electroactive film. Four important parameters are identified: electrolyte composition, (co)polymer composition, prior film history and experimental time scale.

AB - Electrochemical quartz crystal microbalance measurements are reported for redox switching of thin films of three macromolecule‐metal complexes: poly(vinylferrocene) (PVF), 10% osmium‐functionalized poly(vinylpyridine) (Os‐PVP), and 10% osmium functionalized poly(vinylpyridine‐co‐styrene) (Os‐PVP‐co‐PS). The data provide insight into the ion and solvent transfer processes associated with electron transfer between the electrode and the electroactive film. Four important parameters are identified: electrolyte composition, (co)polymer composition, prior film history and experimental time scale.

UR - https://www.scopus.com/pages/publications/84985337622

U2 - 10.1002/masy.19940800122

DO - 10.1002/masy.19940800122

M3 - Article

AN - SCOPUS:84985337622

SN - 1022-1360

VL - 80

SP - 323

EP - 335

JO - Macromolecular Symposia

JF - Macromolecular Symposia

IS - 1

ER -

Electrochemical quartz crystal microbalance studies of redox polymer films

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