Effect of absorption of low-molecular-weight compounds by some polymer flocculants

Tatyana B. Zheftonozhskaya; Olga O. Romankevich; Vladimir G. Syromyatnikov; Leonid A. Bulavin; Vladislav Yu Kudrya; Tymish Yu Ogul'chansky; Valeriy M. Yashchuk

doi:10.1002/masy.19971140135

Effect of absorption of low-molecular-weight compounds by some polymer flocculants

Tatyana B. Zheftonozhskaya
, Olga O. Romankevich
, Vladimir G. Syromyatnikov
, Leonid A. Bulavin
, Vladislav Yu Kudrya
, Tymish Yu Ogul'chansky
, Valeriy M. Yashchuk

Department of Chemical and Biological Engineering

Kyiv National Taras Shevchenko University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The sorption properties of the intramolecular complex - poly(acrylamide) to poly(vinyl alcohol) grafted copolymer (PVA-PAA_N) in block state were investigated with respect to a number of compounds. The relatively small molecules of phenol, phenylalanine in water solution as well as nitrobenzene in hexane are strongly absorbed by PVA-PAA_N films. The large humine acid molecules (sizes are larger by more than ≈ 10 times) are absorbed by PVA-PAA_N very weakly. It was determined the absorption influence on the character of polymer film solution. In a number of cases the oscillation of the dilution and sorption were observed when determining the critical concentrations of guest molecules in the upper layer of polymer films were achieved. The possible mechanisms of absorption were discussed.

Original language	English
Pages (from-to)	263-269
Number of pages	7
Journal	Macromolecular Symposia
Volume	114
DOIs	https://doi.org/10.1002/masy.19971140135
State	Published - Feb 1997

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title = "Effect of absorption of low-molecular-weight compounds by some polymer flocculants",

abstract = "The sorption properties of the intramolecular complex - poly(acrylamide) to poly(vinyl alcohol) grafted copolymer (PVA-PAAN) in block state were investigated with respect to a number of compounds. The relatively small molecules of phenol, phenylalanine in water solution as well as nitrobenzene in hexane are strongly absorbed by PVA-PAAN films. The large humine acid molecules (sizes are larger by more than ≈ 10 times) are absorbed by PVA-PAAN very weakly. It was determined the absorption influence on the character of polymer film solution. In a number of cases the oscillation of the dilution and sorption were observed when determining the critical concentrations of guest molecules in the upper layer of polymer films were achieved. The possible mechanisms of absorption were discussed.",

author = "Zheftonozhskaya, \{Tatyana B.\} and Romankevich, \{Olga O.\} and Syromyatnikov, \{Vladimir G.\} and Bulavin, \{Leonid A.\} and Kudrya, \{Vladislav Yu\} and Ogul'chansky, \{Tymish Yu\} and Yashchuk, \{Valeriy M.\}",

year = "1997",

month = feb,

doi = "10.1002/masy.19971140135",

language = "English",

volume = "114",

pages = "263--269",

journal = "Macromolecular Symposia",

issn = "1022-1360",

publisher = "Wiley-VCH Verlag",

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T1 - Effect of absorption of low-molecular-weight compounds by some polymer flocculants

AU - Zheftonozhskaya, Tatyana B.

AU - Romankevich, Olga O.

AU - Syromyatnikov, Vladimir G.

AU - Bulavin, Leonid A.

AU - Kudrya, Vladislav Yu

AU - Ogul'chansky, Tymish Yu

AU - Yashchuk, Valeriy M.

PY - 1997/2

Y1 - 1997/2

N2 - The sorption properties of the intramolecular complex - poly(acrylamide) to poly(vinyl alcohol) grafted copolymer (PVA-PAAN) in block state were investigated with respect to a number of compounds. The relatively small molecules of phenol, phenylalanine in water solution as well as nitrobenzene in hexane are strongly absorbed by PVA-PAAN films. The large humine acid molecules (sizes are larger by more than ≈ 10 times) are absorbed by PVA-PAAN very weakly. It was determined the absorption influence on the character of polymer film solution. In a number of cases the oscillation of the dilution and sorption were observed when determining the critical concentrations of guest molecules in the upper layer of polymer films were achieved. The possible mechanisms of absorption were discussed.

AB - The sorption properties of the intramolecular complex - poly(acrylamide) to poly(vinyl alcohol) grafted copolymer (PVA-PAAN) in block state were investigated with respect to a number of compounds. The relatively small molecules of phenol, phenylalanine in water solution as well as nitrobenzene in hexane are strongly absorbed by PVA-PAAN films. The large humine acid molecules (sizes are larger by more than ≈ 10 times) are absorbed by PVA-PAAN very weakly. It was determined the absorption influence on the character of polymer film solution. In a number of cases the oscillation of the dilution and sorption were observed when determining the critical concentrations of guest molecules in the upper layer of polymer films were achieved. The possible mechanisms of absorption were discussed.

UR - https://www.scopus.com/pages/publications/0642333560

U2 - 10.1002/masy.19971140135

DO - 10.1002/masy.19971140135

M3 - Article

AN - SCOPUS:0642333560

SN - 1022-1360

VL - 114

SP - 263

EP - 269

JO - Macromolecular Symposia

JF - Macromolecular Symposia

ER -

Effect of absorption of low-molecular-weight compounds by some polymer flocculants

Abstract

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