Dynamic acylhydrazone metal ion complex libraries: A mixed-ligand approach to increased selectivity in extraction

Seema Choudhary; Janet R. Morrow

doi:10.1002/1521-3773(20021104)41:21<4096::AID-ANIE4096>3.0.CO;2-0

Dynamic acylhydrazone metal ion complex libraries: A mixed-ligand approach to increased selectivity in extraction

Seema Choudhary
, Janet R. Morrow

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The dynamic nature of metal-ligand interactions facilitates the formation of metal ion acylhydrazone complex libraries. From these libraries, metal ion complexes with two different types of ligands (1-14; R¹≠R²) are shown to have superior extraction properties. Mixed-ligand combinations enhance the selectivity of extraction of Zn¹¹ over Cd¹¹ (see figure).

Original language	English
Pages (from-to)	4096-4098
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	21
DOIs	https://doi.org/10.1002/1521-3773(20021104)41:21<4096::AID-ANIE4096>3.0.CO;2-0
State	Published - Nov 4 2002

Keywords

Cadmium
Combinatorial chemistry
Coordination modes
N ligands
Separation processes
Zinc

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10.1002/1521-3773(20021104)41:21<4096::AID-ANIE4096>3.0.CO;2-0

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abstract = "The dynamic nature of metal-ligand interactions facilitates the formation of metal ion acylhydrazone complex libraries. From these libraries, metal ion complexes with two different types of ligands (1-14; R1≠R2) are shown to have superior extraction properties. Mixed-ligand combinations enhance the selectivity of extraction of Zn11 over Cd11 (see figure).",

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AB - The dynamic nature of metal-ligand interactions facilitates the formation of metal ion acylhydrazone complex libraries. From these libraries, metal ion complexes with two different types of ligands (1-14; R1≠R2) are shown to have superior extraction properties. Mixed-ligand combinations enhance the selectivity of extraction of Zn11 over Cd11 (see figure).

KW - Cadmium

KW - Combinatorial chemistry

KW - Coordination modes

KW - N ligands

KW - Separation processes

KW - Zinc

UR - https://www.scopus.com/pages/publications/0037021056

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DO - 10.1002/1521-3773(20021104)41:21<4096::AID-ANIE4096>3.0.CO;2-0

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Dynamic acylhydrazone metal ion complex libraries: A mixed-ligand approach to increased selectivity in extraction

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Keywords

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