Dual Porous Electrode Membrane Cell for Detection of Nonelectroactive Species in Flowing Streams

Antonin Trojanek; Stanley Bruckenstein

doi:10.1021/ac00145a011

Dual Porous Electrode Membrane Cell for Detection of Nonelectroactive Species in Flowing Streams

Antonin Trojanek
, Stanley Bruckenstein

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A dual electrode detector capable of being used In flowing streams is described. One electrode generates a volatile reagent from a constituent present In the flowing stream, which then reacts with a dissolved analyte also present in the flowing stream. Excess volatile reagent diffuses through a nonwetting porous membrane to a second electrode at which the unreacted volatile reagent is determined by constant potential electrolysis. The utility of this detector Is demonstrated by the determination of allyl alcohol with electrogenerated bromine In the range 23–697 ng of allyl alcohol.

Original language	English
Pages (from-to)	2260-2263
Number of pages	4
Journal	Analytical Chemistry
Volume	59
Issue number	18
DOIs	https://doi.org/10.1021/ac00145a011
State	Published - 1987

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@article{8c01d0f381cf413e86f54ca2cc214953,

title = "Dual Porous Electrode Membrane Cell for Detection of Nonelectroactive Species in Flowing Streams",

abstract = "A dual electrode detector capable of being used In flowing streams is described. One electrode generates a volatile reagent from a constituent present In the flowing stream, which then reacts with a dissolved analyte also present in the flowing stream. Excess volatile reagent diffuses through a nonwetting porous membrane to a second electrode at which the unreacted volatile reagent is determined by constant potential electrolysis. The utility of this detector Is demonstrated by the determination of allyl alcohol with electrogenerated bromine In the range 23–697 ng of allyl alcohol.",

author = "Antonin Trojanek and Stanley Bruckenstein",

year = "1987",

doi = "10.1021/ac00145a011",

language = "English",

volume = "59",

pages = "2260--2263",

journal = "Analytical Chemistry",

issn = "0003-2700",

publisher = "American Chemical Society",

number = "18",

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TY - JOUR

T1 - Dual Porous Electrode Membrane Cell for Detection of Nonelectroactive Species in Flowing Streams

AU - Trojanek, Antonin

AU - Bruckenstein, Stanley

PY - 1987

Y1 - 1987

N2 - A dual electrode detector capable of being used In flowing streams is described. One electrode generates a volatile reagent from a constituent present In the flowing stream, which then reacts with a dissolved analyte also present in the flowing stream. Excess volatile reagent diffuses through a nonwetting porous membrane to a second electrode at which the unreacted volatile reagent is determined by constant potential electrolysis. The utility of this detector Is demonstrated by the determination of allyl alcohol with electrogenerated bromine In the range 23–697 ng of allyl alcohol.

AB - A dual electrode detector capable of being used In flowing streams is described. One electrode generates a volatile reagent from a constituent present In the flowing stream, which then reacts with a dissolved analyte also present in the flowing stream. Excess volatile reagent diffuses through a nonwetting porous membrane to a second electrode at which the unreacted volatile reagent is determined by constant potential electrolysis. The utility of this detector Is demonstrated by the determination of allyl alcohol with electrogenerated bromine In the range 23–697 ng of allyl alcohol.

UR - https://www.scopus.com/pages/publications/33845281944

U2 - 10.1021/ac00145a011

DO - 10.1021/ac00145a011

M3 - Article

AN - SCOPUS:33845281944

SN - 0003-2700

VL - 59

SP - 2260

EP - 2263

JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 18

ER -

Dual Porous Electrode Membrane Cell for Detection of Nonelectroactive Species in Flowing Streams

Abstract

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