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Doppler effect in resonant photoemission from [formula presented]: Correlation between doppler profile and auger emission anisotropy

  • M. Kitajima
  • , K. Ueda
  • , A. De Fanis
  • , T. Furuta
  • , H. Shindo
  • , H. Tanaka
  • , K. Okada
  • , R. Feifel
  • , S. L. Sorensen
  • , F. Gel’mukhanov
  • , A. Baev
  • , H. Ågren
  • Sophia University
  • Tohoku University
  • Japan Synchrotron Radiation Research Institute
  • Hiroshima University
  • Uppsala University
  • Lund University
  • KTH Royal Institute of Technology

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Fragmentation of the [Formula presented] molecule upon F [Formula presented] excitation has been studied by resonant photoemission. The F atomiclike Auger line exhibits the characteristic Doppler profile that depends on the direction of the photoelectron momentum relative to the polarization vector of the radiation as well as on the photon energy. The measured Doppler profiles are analyzed by the model simulation that takes account of the anisotropy of the Auger emission in the molecular frame. The Auger anisotropy extracted from the data decreases with an increase in the [Formula presented] internuclear distance.

Original languageEnglish
JournalPhysical Review Letters
Volume91
Issue number21
DOIs
StatePublished - 2003

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