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Dissolution at the nanoscale: Self-preservation of biominerals

  • Ruikang Tang
  • , Lijun Wang
  • , Christine A. Orme
  • , Tammy Bonstein
  • , Peter J. Bush
  • , George H. Nancollas
    • SUNY Buffalo
    • Lawrence Livermore National Laboratory

    Research output: Contribution to journalArticlepeer-review

    112 Scopus citations

    Abstract

    Dissolution of nanosized crystallites may be inhibited and even suppressed due to their small size. Nanoparticles with size distribution similar to that of critical dissolution pits (see picture) can be kinetically stabilized against further dissolution even in undersaturated solutions. In biological systems, this behavior confers remarkable self-preservation on biominerals in the fluctuating milieu.

    Original languageEnglish
    Pages (from-to)2697-2701
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume43
    Issue number20
    DOIs
    StatePublished - May 10 2004

    Keywords

    • Apatites
    • Bioinorganic
    • Biomineralization
    • Enamel
    • Nanostructures

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