Displacement of Hard Bases from a Soft Center by a Soft Ligand: Reaction of Ir(CO)(OH)(SO4)L2 (L = PPh3, P(p-tolyl)3) with CO and the Crystal Structure of [Ir(CO)3(PPh3)2+][HSO4−]•1/3H2O

Sherri L. Randall; Jeffrey S. Thompson; Lisa A. Buttrey; Joseph W. Ziller; Melvyn Rowen Churchill; Jim D. Atwood

doi:10.1021/om00049a030

Displacement of Hard Bases from a Soft Center by a Soft Ligand: Reaction of Ir(CO)(OH)(SO₄)L₂ (L = PPh₃, P(p-tolyl)₃) with CO and the Crystal Structure of [Ir(CO)₃(PPh₃)₂⁺][HSO₄−]•¹/₃H₂O

Sherri L. Randall
, Jeffrey S. Thompson
, Lisa A. Buttrey
, Joseph W. Ziller
, Melvyn Rowen Churchill
, Jim D. Atwood

Chemistry

SUNY Buffalo
University of California at Irvine

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The iridium(III) complexes Ir(CO)(OH)(SO₄)L₂, L = PPh₃, P(p-tolyl)₃, have been prepared and shown to react with CO, yielding the iridium(I) species [Ir(CO)₃L₂⁺][HSO₄⁻] (L = PPh₃, P(p-tolyl)₃) and CO₂. The species [Ir(CO)₃(PPh₃)₂⁺][HSO₄⁻]-V₃H₂O crystallizes in the centrosymmetric rhombohedral space group R3 [C_3i²; No. 148]. Cell parameters (for the hexagonal setting) are a = 40.938 (7) Å, c = 11.850 (2) Å, V = 17199 Å³, and Z =18. Diffraction data (Mo Kα, 20 = 4.0–45.0°) were collected on a Syntex P2₁ diffractometer, and the structure was refined to R_F = 6.1% for all 4772 unique data (R_F = 4.2% for those 3673 data with |F_o| > 6.0σ (|F_o|)).

Original language	English
Pages (from-to)	683-688
Number of pages	6
Journal	Organometallics
Volume	10
Issue number	3
DOIs	https://doi.org/10.1021/om00049a030
State	Published - Mar 27 1991

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@article{7e098eb1be3142398a023e3a352c5dc3,

title = "Displacement of Hard Bases from a Soft Center by a Soft Ligand: Reaction of Ir(CO)(OH)(SO4)L2 (L = PPh3, P(p-tolyl)3) with CO and the Crystal Structure of [Ir(CO)3(PPh3)2+][HSO4−]•1/3H2O",

abstract = "The iridium(III) complexes Ir(CO)(OH)(SO4)L2, L = PPh3, P(p-tolyl)3, have been prepared and shown to react with CO, yielding the iridium(I) species [Ir(CO)3L2+][HSO4−] (L = PPh3, P(p-tolyl)3) and CO2. The species [Ir(CO)3(PPh3)2+][HSO4−]-V3H2O crystallizes in the centrosymmetric rhombohedral space group R3 [C3i2; No. 148]. Cell parameters (for the hexagonal setting) are a = 40.938 (7) {\AA}, c = 11.850 (2) {\AA}, V = 17199 {\AA}3, and Z =18. Diffraction data (Mo Kα, 20 = 4.0–45.0°) were collected on a Syntex P21 diffractometer, and the structure was refined to RF = 6.1\% for all 4772 unique data (RF = 4.2\% for those 3673 data with |Fo| > 6.0σ (|Fo|)).",

author = "Randall, \{Sherri L.\} and Thompson, \{Jeffrey S.\} and Buttrey, \{Lisa A.\} and Ziller, \{Joseph W.\} and Churchill, \{Melvyn Rowen\} and Atwood, \{Jim D.\}",

year = "1991",

month = mar,

day = "27",

doi = "10.1021/om00049a030",

language = "English",

volume = "10",

pages = "683--688",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "3",

}

Displacement of Hard Bases from a Soft Center by a Soft Ligand: Reaction of Ir(CO)(OH)(SO₄)L₂ (L = PPh₃, P(p-tolyl)₃) with CO and the Crystal Structure of [Ir(CO)₃(PPh₃)₂⁺][HSO₄−]•¹/₃H₂O. / Randall, Sherri L.; Thompson, Jeffrey S.; Buttrey, Lisa A. et al.
In: Organometallics, Vol. 10, No. 3, 27.03.1991, p. 683-688.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Displacement of Hard Bases from a Soft Center by a Soft Ligand

T2 - Reaction of Ir(CO)(OH)(SO4)L2 (L = PPh3, P(p-tolyl)3) with CO and the Crystal Structure of [Ir(CO)3(PPh3)2+][HSO4−]•1/3H2O

AU - Randall, Sherri L.

AU - Thompson, Jeffrey S.

AU - Buttrey, Lisa A.

AU - Ziller, Joseph W.

AU - Churchill, Melvyn Rowen

AU - Atwood, Jim D.

PY - 1991/3/27

Y1 - 1991/3/27

N2 - The iridium(III) complexes Ir(CO)(OH)(SO4)L2, L = PPh3, P(p-tolyl)3, have been prepared and shown to react with CO, yielding the iridium(I) species [Ir(CO)3L2+][HSO4−] (L = PPh3, P(p-tolyl)3) and CO2. The species [Ir(CO)3(PPh3)2+][HSO4−]-V3H2O crystallizes in the centrosymmetric rhombohedral space group R3 [C3i2; No. 148]. Cell parameters (for the hexagonal setting) are a = 40.938 (7) Å, c = 11.850 (2) Å, V = 17199 Å3, and Z =18. Diffraction data (Mo Kα, 20 = 4.0–45.0°) were collected on a Syntex P21 diffractometer, and the structure was refined to RF = 6.1% for all 4772 unique data (RF = 4.2% for those 3673 data with |Fo| > 6.0σ (|Fo|)).

AB - The iridium(III) complexes Ir(CO)(OH)(SO4)L2, L = PPh3, P(p-tolyl)3, have been prepared and shown to react with CO, yielding the iridium(I) species [Ir(CO)3L2+][HSO4−] (L = PPh3, P(p-tolyl)3) and CO2. The species [Ir(CO)3(PPh3)2+][HSO4−]-V3H2O crystallizes in the centrosymmetric rhombohedral space group R3 [C3i2; No. 148]. Cell parameters (for the hexagonal setting) are a = 40.938 (7) Å, c = 11.850 (2) Å, V = 17199 Å3, and Z =18. Diffraction data (Mo Kα, 20 = 4.0–45.0°) were collected on a Syntex P21 diffractometer, and the structure was refined to RF = 6.1% for all 4772 unique data (RF = 4.2% for those 3673 data with |Fo| > 6.0σ (|Fo|)).

UR - https://www.scopus.com/pages/publications/0041863556

U2 - 10.1021/om00049a030

DO - 10.1021/om00049a030

M3 - Article

AN - SCOPUS:0041863556

SN - 0276-7333

VL - 10

SP - 683

EP - 688

JO - Organometallics

JF - Organometallics

IS - 3

ER -

Displacement of Hard Bases from a Soft Center by a Soft Ligand: Reaction of Ir(CO)(OH)(SO₄)L₂ (L = PPh₃, P(p-tolyl)₃) with CO and the Crystal Structure of [Ir(CO)₃(PPh₃)₂⁺][HSO₄−]•¹/₃H₂O

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