Determination of the Transduction Mechanism for Optical Sensors Based on Rhodamine 6G Impregnated Perfluorosulfonate Films Using Steady-State and Frequency-Domain Fluorescence

Kevin S. Litwiler; Pamela M. Kluczynski; Frank V. Bright

doi:10.1021/ac00008a012

Determination of the Transduction Mechanism for Optical Sensors Based on Rhodamine 6G Impregnated Perfluorosulfonate Films Using Steady-State and Frequency-Domain Fluorescence

Kevin S. Litwiler
, Pamela M. Kluczynski
, Frank V. Bright

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Multifrequency phase-modulation fluorescence spectroscopy is used to Investigate the dynamics of thin Nation films Impregnated with rhodamine 6G (R6G). Using this approach, we explore the photophyslcs of these films as a function of R6G concentration, water content, Cu(II) quencher concentration, and film preparation procedure. From this, we infer how these films function as chemical recognition elements in fiber-optic-based sensors. The decay kinetics for all films studied are best described by a simple bioexponential decay law, a result of ground-state dimer formation.

Original language	English
Pages (from-to)	797-802
Number of pages	6
Journal	Analytical Chemistry
Volume	63
Issue number	8
DOIs	https://doi.org/10.1021/ac00008a012
State	Published - Apr 1 1991

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10.1021/ac00008a012

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title = "Determination of the Transduction Mechanism for Optical Sensors Based on Rhodamine 6G Impregnated Perfluorosulfonate Films Using Steady-State and Frequency-Domain Fluorescence",

abstract = "Multifrequency phase-modulation fluorescence spectroscopy is used to Investigate the dynamics of thin Nation films Impregnated with rhodamine 6G (R6G). Using this approach, we explore the photophyslcs of these films as a function of R6G concentration, water content, Cu(II) quencher concentration, and film preparation procedure. From this, we infer how these films function as chemical recognition elements in fiber-optic-based sensors. The decay kinetics for all films studied are best described by a simple bioexponential decay law, a result of ground-state dimer formation.",

author = "Litwiler, \{Kevin S.\} and Kluczynski, \{Pamela M.\} and Bright, \{Frank V.\}",

year = "1991",

month = apr,

day = "1",

doi = "10.1021/ac00008a012",

language = "English",

volume = "63",

pages = "797--802",

journal = "Analytical Chemistry",

issn = "0003-2700",

publisher = "American Chemical Society",

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Determination of the Transduction Mechanism for Optical Sensors Based on Rhodamine 6G Impregnated Perfluorosulfonate Films Using Steady-State and Frequency-Domain Fluorescence. / Litwiler, Kevin S.; Kluczynski, Pamela M.; Bright, Frank V.
In: Analytical Chemistry, Vol. 63, No. 8, 01.04.1991, p. 797-802.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Determination of the Transduction Mechanism for Optical Sensors Based on Rhodamine 6G Impregnated Perfluorosulfonate Films Using Steady-State and Frequency-Domain Fluorescence

AU - Litwiler, Kevin S.

AU - Kluczynski, Pamela M.

AU - Bright, Frank V.

PY - 1991/4/1

Y1 - 1991/4/1

N2 - Multifrequency phase-modulation fluorescence spectroscopy is used to Investigate the dynamics of thin Nation films Impregnated with rhodamine 6G (R6G). Using this approach, we explore the photophyslcs of these films as a function of R6G concentration, water content, Cu(II) quencher concentration, and film preparation procedure. From this, we infer how these films function as chemical recognition elements in fiber-optic-based sensors. The decay kinetics for all films studied are best described by a simple bioexponential decay law, a result of ground-state dimer formation.

AB - Multifrequency phase-modulation fluorescence spectroscopy is used to Investigate the dynamics of thin Nation films Impregnated with rhodamine 6G (R6G). Using this approach, we explore the photophyslcs of these films as a function of R6G concentration, water content, Cu(II) quencher concentration, and film preparation procedure. From this, we infer how these films function as chemical recognition elements in fiber-optic-based sensors. The decay kinetics for all films studied are best described by a simple bioexponential decay law, a result of ground-state dimer formation.

UR - https://www.scopus.com/pages/publications/0000856892

U2 - 10.1021/ac00008a012

DO - 10.1021/ac00008a012

M3 - Article

AN - SCOPUS:0000856892

SN - 0003-2700

VL - 63

SP - 797

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JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 8

ER -

Determination of the Transduction Mechanism for Optical Sensors Based on Rhodamine 6G Impregnated Perfluorosulfonate Films Using Steady-State and Frequency-Domain Fluorescence

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