Determination of Hg(I) Adsorption Accompanying the Coulostatic Underpotential Deposition of Mercury on Gold Using the Quartz Crystal Microbalance

Michael Shay; Stanley Bruckenstein

doi:10.1021/la00085a056

Determination of Hg(I) Adsorption Accompanying the Coulostatic Underpotential Deposition of Mercury on Gold Using the Quartz Crystal Microbalance

Michael Shay
, Stanley Bruckenstein

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Emersion experiments were carried out from 2 X 10^-5M Hg(I) solutions of 0.2 M H₂SO₄ at the gold electrode of a quartz crystal microbalance. Prior to emersion, the gold electrode was open-circuited in this solution and one monolayer, 1.7 X 10^-9g-atom cm^-2, of underpotential Hg(0) deposited by a coulostatic process. Also, 0.29 X 10^-9g-mol cm^-2 of Hg(I) bisulfate was adsorbed.

Original language	English
Pages (from-to)	280-282
Number of pages	3
Journal	Langmuir
Volume	5
Issue number	1
DOIs	https://doi.org/10.1021/la00085a056
State	Published - Jan 1 1989

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title = "Determination of Hg(I) Adsorption Accompanying the Coulostatic Underpotential Deposition of Mercury on Gold Using the Quartz Crystal Microbalance",

abstract = "Emersion experiments were carried out from 2 X 10-5M Hg(I) solutions of 0.2 M H2SO4 at the gold electrode of a quartz crystal microbalance. Prior to emersion, the gold electrode was open-circuited in this solution and one monolayer, 1.7 X 10-9g-atom cm-2, of underpotential Hg(0) deposited by a coulostatic process. Also, 0.29 X 10-9g-mol cm-2 of Hg(I) bisulfate was adsorbed.",

author = "Michael Shay and Stanley Bruckenstein",

year = "1989",

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AU - Shay, Michael

AU - Bruckenstein, Stanley

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Y1 - 1989/1/1

N2 - Emersion experiments were carried out from 2 X 10-5M Hg(I) solutions of 0.2 M H2SO4 at the gold electrode of a quartz crystal microbalance. Prior to emersion, the gold electrode was open-circuited in this solution and one monolayer, 1.7 X 10-9g-atom cm-2, of underpotential Hg(0) deposited by a coulostatic process. Also, 0.29 X 10-9g-mol cm-2 of Hg(I) bisulfate was adsorbed.

AB - Emersion experiments were carried out from 2 X 10-5M Hg(I) solutions of 0.2 M H2SO4 at the gold electrode of a quartz crystal microbalance. Prior to emersion, the gold electrode was open-circuited in this solution and one monolayer, 1.7 X 10-9g-atom cm-2, of underpotential Hg(0) deposited by a coulostatic process. Also, 0.29 X 10-9g-mol cm-2 of Hg(I) bisulfate was adsorbed.

UR - https://www.scopus.com/pages/publications/4544328952

U2 - 10.1021/la00085a056

DO - 10.1021/la00085a056

M3 - Article

AN - SCOPUS:4544328952

SN - 0743-7463

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JO - Langmuir

JF - Langmuir

IS - 1

ER -

Determination of Hg(I) Adsorption Accompanying the Coulostatic Underpotential Deposition of Mercury on Gold Using the Quartz Crystal Microbalance

Abstract

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