Abstract
The rates of capture of the 1-(4-methylthiophenyl)-2,2,2-trifluoroethyl carbocation by alkylamines in a desolvation-limited reaction decrease with increasing amine pKa, and are up to 200 times slower than diffusion-limited carbocation capture by azide.
| Original language | English |
|---|---|
| Pages (from-to) | 1768-1769 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society D: Chemical Communications |
| Issue number | 23 |
| DOIs | |
| State | Published - 1987 |
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