Cycloheptadiene Ring Synthesis by Tandem Intermolecular Enyne Metathesis

Amol A. Kulkarni; Steven T. Diver

doi:10.1021/ol035246y

Cycloheptadiene Ring Synthesis by Tandem Intermolecular Enyne Metathesis

Amol A. Kulkarni
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

(Equation presented) The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne.

Original language	English
Pages (from-to)	3463-3466
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	19
DOIs	https://doi.org/10.1021/ol035246y
State	Published - Sep 18 2003

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@article{246a334b9bdd4253b45e910788c8d910,

title = "Cycloheptadiene Ring Synthesis by Tandem Intermolecular Enyne Metathesis",

abstract = "(Equation presented) The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne.",

author = "Kulkarni, \{Amol A.\} and Diver, \{Steven T.\}",

year = "2003",

month = sep,

day = "18",

doi = "10.1021/ol035246y",

language = "English",

volume = "5",

pages = "3463--3466",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Cycloheptadiene Ring Synthesis by Tandem Intermolecular Enyne Metathesis

AU - Kulkarni, Amol A.

AU - Diver, Steven T.

PY - 2003/9/18

Y1 - 2003/9/18

N2 - (Equation presented) The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne.

AB - (Equation presented) The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne.

UR - https://www.scopus.com/pages/publications/0345687228

U2 - 10.1021/ol035246y

DO - 10.1021/ol035246y

M3 - Article

C2 - 12967300

AN - SCOPUS:0345687228

SN - 1523-7060

VL - 5

SP - 3463

EP - 3466

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Cycloheptadiene Ring Synthesis by Tandem Intermolecular Enyne Metathesis

Abstract

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