Crystal structure of the co-crystal of 5-aminoisophthalic acid and 1,2-bis(pyridin-4-yl)ethene

Scott C. McGuire; Steven C. Travis; Daniel W. Tuohey; Thomas J. Deering; Bob Martin; Jordan M. Cox; Jason B. Benedict

doi:10.1107/S2056989016005259

Crystal structure of the co-crystal of 5-aminoisophthalic acid and 1,2-bis(pyridin-4-yl)ethene

Scott C. McGuire
, Steven C. Travis
, Daniel W. Tuohey
, Thomas J. Deering
, Bob Martin
, Jordan M. Cox
, Jason B. Benedict

Chemistry

764 Natural Sciences Complex
345 Natural Sciences Complex

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

In the title 1:1 co-crystal, C12H10N2 C8H7NO4, the bipyridine moiety shows whole-molecule disorder over two sets of sites in a 0.588(3): 0.412(3) ratio. In the crystal, the components form hydrogen-bonded sheets linked by N - H⋯O and O - H⋯N interactions, which stack along the a axis. A comparison to a related and previously published co-crystal of 5-amino-isophthalic acid and the shorter 4,4′-bipryidine is presented.

Original language	English
Pages (from-to)	639-642
Number of pages	4
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
DOIs	https://doi.org/10.1107/S2056989016005259
State	Published - May 1 2016

Keywords

1 2-bis(pyridin-4-yl)ethene (BE)
5-aminoisophthalic acid
5AIA
co-crystal
crystal structure
hydrogen bonding

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10.1107/S2056989016005259

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title = "Crystal structure of the co-crystal of 5-aminoisophthalic acid and 1,2-bis(pyridin-4-yl)ethene",

abstract = "In the title 1:1 co-crystal, C12H10N2 C8H7NO4, the bipyridine moiety shows whole-molecule disorder over two sets of sites in a 0.588(3): 0.412(3) ratio. In the crystal, the components form hydrogen-bonded sheets linked by N - H⋯O and O - H⋯N interactions, which stack along the a axis. A comparison to a related and previously published co-crystal of 5-amino-isophthalic acid and the shorter 4,4′-bipryidine is presented.",

keywords = "1 2-bis(pyridin-4-yl)ethene (BE), 5-aminoisophthalic acid, 5AIA, co-crystal, crystal structure, hydrogen bonding",

author = "McGuire, \{Scott C.\} and Travis, \{Steven C.\} and Tuohey, \{Daniel W.\} and Deering, \{Thomas J.\} and Bob Martin and Cox, \{Jordan M.\} and Benedict, \{Jason B.\}",

note = "Publisher Copyright: {\textcopyright} 2016.",

year = "2016",

month = may,

day = "1",

doi = "10.1107/S2056989016005259",

language = "English",

volume = "72",

pages = "639--642",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Crystal structure of the co-crystal of 5-aminoisophthalic acid and 1,2-bis(pyridin-4-yl)ethene

AU - McGuire, Scott C.

AU - Travis, Steven C.

AU - Tuohey, Daniel W.

AU - Deering, Thomas J.

AU - Martin, Bob

AU - Cox, Jordan M.

AU - Benedict, Jason B.

PY - 2016/5/1

Y1 - 2016/5/1

N2 - In the title 1:1 co-crystal, C12H10N2 C8H7NO4, the bipyridine moiety shows whole-molecule disorder over two sets of sites in a 0.588(3): 0.412(3) ratio. In the crystal, the components form hydrogen-bonded sheets linked by N - H⋯O and O - H⋯N interactions, which stack along the a axis. A comparison to a related and previously published co-crystal of 5-amino-isophthalic acid and the shorter 4,4′-bipryidine is presented.

AB - In the title 1:1 co-crystal, C12H10N2 C8H7NO4, the bipyridine moiety shows whole-molecule disorder over two sets of sites in a 0.588(3): 0.412(3) ratio. In the crystal, the components form hydrogen-bonded sheets linked by N - H⋯O and O - H⋯N interactions, which stack along the a axis. A comparison to a related and previously published co-crystal of 5-amino-isophthalic acid and the shorter 4,4′-bipryidine is presented.

KW - 1 2-bis(pyridin-4-yl)ethene (BE)

KW - 5-aminoisophthalic acid

KW - 5AIA

KW - co-crystal

KW - crystal structure

KW - hydrogen bonding

UR - https://www.scopus.com/pages/publications/84969506990

U2 - 10.1107/S2056989016005259

DO - 10.1107/S2056989016005259

M3 - Article

AN - SCOPUS:84969506990

SN - 2056-9890

VL - 72

SP - 639

EP - 642

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

ER -

Crystal structure of the co-crystal of 5-aminoisophthalic acid and 1,2-bis(pyridin-4-yl)ethene

Abstract

Keywords

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