Criteria governing ion and solvent transport rates in electroactive polymers: The existence of kinetic permselectivity

A. Robert Hillman; David C. Loveday; Stanley Bruckenstein; C. Paul Wilde

doi:10.1039/FT9908600437

Criteria governing ion and solvent transport rates in electroactive polymers: The existence of kinetic permselectivity

A. Robert Hillman
, David C. Loveday
, Stanley Bruckenstein
, C. Paul Wilde

Chemistry

University of Bristol
SUNY Buffalo
University of Ottawa

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Ion and solvent transport in polythionine and polyvinylferrocene films have been monitored under transient conditions using the electrochemical quartz crystal microbalance. Film sources of required species are utilized before solution-phase sources. Potential gradients within the film influence ion motion, resulting in a diversity of transport rates which can give rise to transient permselectivity.

Original language	English
Pages (from-to)	437-438
Number of pages	2
Journal	Journal of the Chemical Society - Faraday Transactions
Volume	86
Issue number	2
DOIs	https://doi.org/10.1039/FT9908600437
State	Published - 1990

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10.1039/FT9908600437

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title = "Criteria governing ion and solvent transport rates in electroactive polymers: The existence of kinetic permselectivity",

abstract = "Ion and solvent transport in polythionine and polyvinylferrocene films have been monitored under transient conditions using the electrochemical quartz crystal microbalance. Film sources of required species are utilized before solution-phase sources. Potential gradients within the film influence ion motion, resulting in a diversity of transport rates which can give rise to transient permselectivity.",

author = "Hillman, \{A. Robert\} and Loveday, \{David C.\} and Stanley Bruckenstein and Wilde, \{C. Paul\}",

year = "1990",

doi = "10.1039/FT9908600437",

language = "English",

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pages = "437--438",

journal = "Journal of the Chemical Society - Faraday Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Criteria governing ion and solvent transport rates in electroactive polymers

T2 - The existence of kinetic permselectivity

AU - Hillman, A. Robert

AU - Loveday, David C.

AU - Bruckenstein, Stanley

AU - Wilde, C. Paul

PY - 1990

Y1 - 1990

N2 - Ion and solvent transport in polythionine and polyvinylferrocene films have been monitored under transient conditions using the electrochemical quartz crystal microbalance. Film sources of required species are utilized before solution-phase sources. Potential gradients within the film influence ion motion, resulting in a diversity of transport rates which can give rise to transient permselectivity.

AB - Ion and solvent transport in polythionine and polyvinylferrocene films have been monitored under transient conditions using the electrochemical quartz crystal microbalance. Film sources of required species are utilized before solution-phase sources. Potential gradients within the film influence ion motion, resulting in a diversity of transport rates which can give rise to transient permselectivity.

UR - https://www.scopus.com/pages/publications/0003697798

U2 - 10.1039/FT9908600437

DO - 10.1039/FT9908600437

M3 - Article

AN - SCOPUS:0003697798

SN - 0956-5000

VL - 86

SP - 437

EP - 438

JO - Journal of the Chemical Society - Faraday Transactions

JF - Journal of the Chemical Society - Faraday Transactions

IS - 2

ER -

Criteria governing ion and solvent transport rates in electroactive polymers: The existence of kinetic permselectivity

Abstract

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