Copper-promoted and copper-catalyzed intermolecular alkene diamination

Fatima C. Sequeira; Benjamin W. Turnpenny; Sherry R. Chemler

doi:10.1002/anie.201003499

Copper-promoted and copper-catalyzed intermolecular alkene diamination

Fatima C. Sequeira
, Benjamin W. Turnpenny
, Sherry R. Chemler

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

198 Scopus citations

Abstract

Simply copper: Copper(II)-promoted intra- and intermolecular olefin diaminations bring together two differently functionalized amines into a vicinal relationship. High diastereoselectivity was obtained with chiral alkenes and results of the asymmetric catalysis are promising.

Original language	English
Pages (from-to)	6365-6368
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	36
DOIs	https://doi.org/10.1002/anie.201003499
State	Published - Aug 23 2010

Keywords

Alkenes
Copper
Diamination
Homogeneous catalysis
Nitrogen heterocycles

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10.1002/anie.201003499

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title = "Copper-promoted and copper-catalyzed intermolecular alkene diamination",

abstract = "Simply copper: Copper(II)-promoted intra- and intermolecular olefin diaminations bring together two differently functionalized amines into a vicinal relationship. High diastereoselectivity was obtained with chiral alkenes and results of the asymmetric catalysis are promising.",

keywords = "Alkenes, Copper, Diamination, Homogeneous catalysis, Nitrogen heterocycles",

author = "Sequeira, \{Fatima C.\} and Turnpenny, \{Benjamin W.\} and Chemler, \{Sherry R.\}",

year = "2010",

month = aug,

day = "23",

doi = "10.1002/anie.201003499",

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T1 - Copper-promoted and copper-catalyzed intermolecular alkene diamination

AU - Sequeira, Fatima C.

AU - Turnpenny, Benjamin W.

AU - Chemler, Sherry R.

PY - 2010/8/23

Y1 - 2010/8/23

N2 - Simply copper: Copper(II)-promoted intra- and intermolecular olefin diaminations bring together two differently functionalized amines into a vicinal relationship. High diastereoselectivity was obtained with chiral alkenes and results of the asymmetric catalysis are promising.

AB - Simply copper: Copper(II)-promoted intra- and intermolecular olefin diaminations bring together two differently functionalized amines into a vicinal relationship. High diastereoselectivity was obtained with chiral alkenes and results of the asymmetric catalysis are promising.

KW - Alkenes

KW - Copper

KW - Diamination

KW - Homogeneous catalysis

KW - Nitrogen heterocycles

UR - https://www.scopus.com/pages/publications/77956047665

U2 - 10.1002/anie.201003499

DO - 10.1002/anie.201003499

M3 - Article

C2 - 20672278

AN - SCOPUS:77956047665

SN - 1433-7851

VL - 49

SP - 6365

EP - 6368

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Copper-promoted and copper-catalyzed intermolecular alkene diamination

Abstract

Keywords

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