Copper dioxygen (bio)inorganic chemistry

Edward I. Solomon; Jake W. Ginsbach; David E. Heppner; Matthew T. Kieber-Emmons; Christian H. Kjaergaard; Pieter J. Smeets; Li Tian; Julia S. Woertink

doi:10.1039/c005500j

Copper dioxygen (bio)inorganic chemistry

Edward I. Solomon
, Jake W. Ginsbach
, David E. Heppner
, Matthew T. Kieber-Emmons
, Christian H. Kjaergaard
, Pieter J. Smeets
, Li Tian
, Julia S. Woertink

Chemistry

Stanford University

Research output: Contribution to journal › Review article › peer-review

157 Scopus citations

Abstract

Cu/O₂ intermediates in biological, homogeneous, and heterogeneous catalysts exhibit unique spectral features that reflect novel geometric and electronic structures that make significant contributions to reactivity. This review considers how the respective intermediate electronic structures overcome the spin-forbidden nature of O₂ binding, activate O₂ for electrophilic aromatic attack and H-atom abstraction, catalyze the 4 e^- reduction of O₂ to H₂O, and discusses the role of exchange coupling between Cu ions in determining reactivity.

Original language	English
Pages (from-to)	11-39
Number of pages	29
Journal	Faraday Discussions
Volume	148
DOIs	https://doi.org/10.1039/c005500j
State	Published - 2011

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title = "Copper dioxygen (bio)inorganic chemistry",

abstract = "Cu/O2 intermediates in biological, homogeneous, and heterogeneous catalysts exhibit unique spectral features that reflect novel geometric and electronic structures that make significant contributions to reactivity. This review considers how the respective intermediate electronic structures overcome the spin-forbidden nature of O2 binding, activate O2 for electrophilic aromatic attack and H-atom abstraction, catalyze the 4 e- reduction of O2 to H2O, and discusses the role of exchange coupling between Cu ions in determining reactivity.",

author = "Solomon, \{Edward I.\} and Ginsbach, \{Jake W.\} and Heppner, \{David E.\} and Kieber-Emmons, \{Matthew T.\} and Kjaergaard, \{Christian H.\} and Smeets, \{Pieter J.\} and Li Tian and Woertink, \{Julia S.\}",

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language = "English",

volume = "148",

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journal = "Faraday Discussions",

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T1 - Copper dioxygen (bio)inorganic chemistry

AU - Solomon, Edward I.

AU - Ginsbach, Jake W.

AU - Heppner, David E.

AU - Kieber-Emmons, Matthew T.

AU - Kjaergaard, Christian H.

AU - Smeets, Pieter J.

AU - Tian, Li

AU - Woertink, Julia S.

PY - 2011

Y1 - 2011

N2 - Cu/O2 intermediates in biological, homogeneous, and heterogeneous catalysts exhibit unique spectral features that reflect novel geometric and electronic structures that make significant contributions to reactivity. This review considers how the respective intermediate electronic structures overcome the spin-forbidden nature of O2 binding, activate O2 for electrophilic aromatic attack and H-atom abstraction, catalyze the 4 e- reduction of O2 to H2O, and discusses the role of exchange coupling between Cu ions in determining reactivity.

AB - Cu/O2 intermediates in biological, homogeneous, and heterogeneous catalysts exhibit unique spectral features that reflect novel geometric and electronic structures that make significant contributions to reactivity. This review considers how the respective intermediate electronic structures overcome the spin-forbidden nature of O2 binding, activate O2 for electrophilic aromatic attack and H-atom abstraction, catalyze the 4 e- reduction of O2 to H2O, and discusses the role of exchange coupling between Cu ions in determining reactivity.

UR - https://www.scopus.com/pages/publications/79952270656

U2 - 10.1039/c005500j

DO - 10.1039/c005500j

M3 - Review article

C2 - 21322475

AN - SCOPUS:79952270656

SN - 1359-6640

VL - 148

SP - 11

EP - 39

JO - Faraday Discussions

JF - Faraday Discussions

ER -

Copper dioxygen (bio)inorganic chemistry

Abstract

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