Controlled/living free-radical polymerization under very high pressure

Javid Rzayev; Jacques Penelle

doi:10.1021/ma011668g

Controlled/living free-radical polymerization under very high pressure

Javid Rzayev
, Jacques Penelle

Chemistry

University of Massachusetts

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

The reversible addition-fragmentation chain-transfer (RAFT) polymerization of a sterically hindered "nonpolymerizable" monomer, methyl acrylate (MEA), was achieved under high-pressure conditions, extending the pool of monomers available for living free-radical polymerization techniques. Well-controlled polymers with narrow polydispersities were obtained. The efficient reinitiation with styrene resulted in a poly(MEA-b-styrene) diblock copolymer.

Original language	English
Pages (from-to)	1489-1490
Number of pages	2
Journal	Macromolecules
Volume	35
Issue number	5
DOIs	https://doi.org/10.1021/ma011668g
State	Published - Feb 26 2002

Access to Document

10.1021/ma011668g

Cite this

@article{fcaff061ae944453a5fef09216de56c6,

title = "Controlled/living free-radical polymerization under very high pressure",

abstract = "The reversible addition-fragmentation chain-transfer (RAFT) polymerization of a sterically hindered {"}nonpolymerizable{"} monomer, methyl acrylate (MEA), was achieved under high-pressure conditions, extending the pool of monomers available for living free-radical polymerization techniques. Well-controlled polymers with narrow polydispersities were obtained. The efficient reinitiation with styrene resulted in a poly(MEA-b-styrene) diblock copolymer.",

author = "Javid Rzayev and Jacques Penelle",

year = "2002",

month = feb,

day = "26",

doi = "10.1021/ma011668g",

language = "English",

volume = "35",

pages = "1489--1490",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Controlled/living free-radical polymerization under very high pressure

AU - Rzayev, Javid

AU - Penelle, Jacques

PY - 2002/2/26

Y1 - 2002/2/26

N2 - The reversible addition-fragmentation chain-transfer (RAFT) polymerization of a sterically hindered "nonpolymerizable" monomer, methyl acrylate (MEA), was achieved under high-pressure conditions, extending the pool of monomers available for living free-radical polymerization techniques. Well-controlled polymers with narrow polydispersities were obtained. The efficient reinitiation with styrene resulted in a poly(MEA-b-styrene) diblock copolymer.

AB - The reversible addition-fragmentation chain-transfer (RAFT) polymerization of a sterically hindered "nonpolymerizable" monomer, methyl acrylate (MEA), was achieved under high-pressure conditions, extending the pool of monomers available for living free-radical polymerization techniques. Well-controlled polymers with narrow polydispersities were obtained. The efficient reinitiation with styrene resulted in a poly(MEA-b-styrene) diblock copolymer.

UR - https://www.scopus.com/pages/publications/0037177017

U2 - 10.1021/ma011668g

DO - 10.1021/ma011668g

M3 - Article

AN - SCOPUS:0037177017

SN - 0024-9297

VL - 35

SP - 1489

EP - 1490

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

Controlled/living free-radical polymerization under very high pressure

Abstract

Access to Document

Other files and links

Fingerprint

Cite this