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Complete active space wavefunction-based analysis of magnetization and electronic structure

  • SUNY Buffalo
  • Université Toulouse III - Paul Sabatier

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

9 Scopus citations

Abstract

A theoretical framework for the generation of natural orbitals, natural spin orbitals, as well as orbital- and spin-magnetizations, from multi-configurational ab initio wavefunction calculations including spin-orbit coupling is presented. Selected case studies show how these computational orbital and magnetization tools can be used to interpret and rationalize the magnetic properties of complexes containing transition metals, lanthanides, and actinides.

Original languageEnglish
Title of host publicationTopics in Organometallic Chemistry
PublisherSpringer
Pages355-390
Number of pages36
DOIs
StatePublished - 2019

Publication series

NameTopics in Organometallic Chemistry
Volume64
ISSN (Print)1436-6002
ISSN (Electronic)1616-8534

Keywords

  • Electron spin Hamiltonian
  • Magnetization
  • Natural orbitals
  • Spin Hamiltonian
  • Spin orbit coupling
  • Wavefunction calculations
  • Zeeman interaction

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