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CHARGE DENSITY ANOMALIES IN Si AND InSb PRECEDING THE HIGH PRESSURE TRANSITION.

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Abstract

The intensity of the (222) forbidden x-ray reflection in Si and InSb was measured as a function of high hydrostatic pressure. A few kbars prior to the pressure induced transformation to the metallic beta -Sn structure the (222) intensity decreases sharply. This anomalous behavior is interpreted as being due either to smearing of the valence bond-charge in anticipation of the metallic state, or to increased anharmonicity in the thermal vibrations. The role of zone boundary TA phonons is considered.

Original languageEnglish
Pages (from-to)564-566
Number of pages3
JournalPhysica B: Physics of Condensed Matter & C: Atomic, Molecular and Plasma Physics, Optics
Volume117-118
Issue numberPt II
StatePublished - 1982
EventProc of the Int Conf on the Phys of Semicond, 16th - Montpellier, Fr
Duration: Sep 6 1982Sep 10 1982

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