Cation participation during the redox switching of poly(vinylferrocene) films in aqueous 0.05 M perchlorate solutions: Part 1: Cyclic voltammetry and the EQCM

I. Jureviciute; S. Bruckenstein; A. R. Hillman

doi:10.1016/j.electacta.2005.02.155

Cation participation during the redox switching of poly(vinylferrocene) films in aqueous 0.05 M perchlorate solutions: Part 1: Cyclic voltammetry and the EQCM

I. Jureviciute
, S. Bruckenstein
, A. R. Hillman

Chemistry

Center for Physical Sciences and Technology
University of Leicester

Research output: Contribution to journal › Conference article › peer-review

9 Scopus citations

Abstract

Mobile species transfer accompanying the redox switching of poly(vinylferrocene) (PVF) in aqueous perchlorate solutions of four cations was investigated using the electrochemical quartz crystal microbalance (EQCM). Cyclic voltammetry in 0.05 M solutions containing hydronium, sodium, rubidium or tetraethylammonium cation was employed. The mass transients could not be explained solely in terms of anion and solvent transport processes. EQCM transient data showed that the cation as well as perchlorate and water transport participated in the redox switching process in the four bathing solutions. Results and interpretation of the experimental approach are presented.

Original language	English
Pages (from-to)	2351-2357
Number of pages	7
Journal	Electrochimica Acta
Volume	51
Issue number	11
DOIs	https://doi.org/10.1016/j.electacta.2005.02.155
State	Published - Feb 15 2006
Event	Electrode Processes Selection of Papers from the International Conference - Szczyrk, Poland Duration: Sep 15 2004 → Sep 18 2004

Keywords

Co-ions
EQCM
Perchlorate
Permselectivity
Poly(vinylferrocene)

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10.1016/j.electacta.2005.02.155

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title = "Cation participation during the redox switching of poly(vinylferrocene) films in aqueous 0.05 M perchlorate solutions: Part 1: Cyclic voltammetry and the EQCM",

abstract = "Mobile species transfer accompanying the redox switching of poly(vinylferrocene) (PVF) in aqueous perchlorate solutions of four cations was investigated using the electrochemical quartz crystal microbalance (EQCM). Cyclic voltammetry in 0.05 M solutions containing hydronium, sodium, rubidium or tetraethylammonium cation was employed. The mass transients could not be explained solely in terms of anion and solvent transport processes. EQCM transient data showed that the cation as well as perchlorate and water transport participated in the redox switching process in the four bathing solutions. Results and interpretation of the experimental approach are presented.",

keywords = "Co-ions, EQCM, Perchlorate, Permselectivity, Poly(vinylferrocene)",

author = "I. Jureviciute and S. Bruckenstein and Hillman, \{A. R.\}",

year = "2006",

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doi = "10.1016/j.electacta.2005.02.155",

language = "English",

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pages = "2351--2357",

journal = "Electrochimica Acta",

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note = "Electrode Processes Selection of Papers from the International Conference ; Conference date: 15-09-2004 Through 18-09-2004",

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TY - JOUR

T1 - Cation participation during the redox switching of poly(vinylferrocene) films in aqueous 0.05 M perchlorate solutions

T2 - Electrode Processes Selection of Papers from the International Conference

AU - Jureviciute, I.

AU - Bruckenstein, S.

AU - Hillman, A. R.

PY - 2006/2/15

Y1 - 2006/2/15

N2 - Mobile species transfer accompanying the redox switching of poly(vinylferrocene) (PVF) in aqueous perchlorate solutions of four cations was investigated using the electrochemical quartz crystal microbalance (EQCM). Cyclic voltammetry in 0.05 M solutions containing hydronium, sodium, rubidium or tetraethylammonium cation was employed. The mass transients could not be explained solely in terms of anion and solvent transport processes. EQCM transient data showed that the cation as well as perchlorate and water transport participated in the redox switching process in the four bathing solutions. Results and interpretation of the experimental approach are presented.

AB - Mobile species transfer accompanying the redox switching of poly(vinylferrocene) (PVF) in aqueous perchlorate solutions of four cations was investigated using the electrochemical quartz crystal microbalance (EQCM). Cyclic voltammetry in 0.05 M solutions containing hydronium, sodium, rubidium or tetraethylammonium cation was employed. The mass transients could not be explained solely in terms of anion and solvent transport processes. EQCM transient data showed that the cation as well as perchlorate and water transport participated in the redox switching process in the four bathing solutions. Results and interpretation of the experimental approach are presented.

KW - Co-ions

KW - EQCM

KW - Perchlorate

KW - Permselectivity

KW - Poly(vinylferrocene)

UR - https://www.scopus.com/pages/publications/31944438682

U2 - 10.1016/j.electacta.2005.02.155

DO - 10.1016/j.electacta.2005.02.155

M3 - Conference article

AN - SCOPUS:31944438682

SN - 0013-4686

VL - 51

SP - 2351

EP - 2357

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 11

Y2 - 15 September 2004 through 18 September 2004

ER -

Cation participation during the redox switching of poly(vinylferrocene) films in aqueous 0.05 M perchlorate solutions: Part 1: Cyclic voltammetry and the EQCM

Abstract

Keywords

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